Copper(I) Bromide-Dimethyl Sulfide 溴化亚铜二甲硫醚

CAS 54678-23-8 MFCD00043295

化学结构图

54678-23-8
SMILES: CSC.[Cu]Br

化学属性

Mol. FormulaCuBr · CH3SCH3
Mol. Weight205.58
Melting Point132°C
Density1.422
TSCANo
Appearance off-white to light-green pwdr.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameCopper(I) Bromide-Dimethyl Sulfide
Synonym Bromo[thiobis[methane]]copper {LY} Bromo[thiobis[methane]]copper {} {LY} Bromo[thiobis[methane]]copper {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number4386581
PubChem Substance ID2724234
CAS Number54678-23-8
EC Number259-292-5
MDL NumberMFCD00043295
Chemical Name Translation溴化亚铜二甲硫醚
InChIKeyPMHQVHHXPFUNSP-UHFFFAOYSA-M
LabNetwork Molecule IDLN00222683
InChIInChI=1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1
Canonical SMILESCSC.[Cu]Br
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学

相关文献及参考

  • 1. Org. Synth. 83 , 80, (2006)
  • Rossiter, B. E. et al.B. E.; Swingle, N. M. Chem. Rev. 92 , 771, (1992)
  • Robert, T.; Velder, J.; Schmalz, H.-G. Angew. Chem. Int. Ed. Engl. 47 , 7718, (2008)
  • Pacheco B.; Piguel, S. et al. Org. Lett. 12 , 4038, (2010) 摘要
  • Fieser 6 ,225 / Fieser 8 ,117 / Fieser 10 ,104 / Fieser 15 ,100 / Fieser 16 ,96
  • Aldrich MSDS 1 , 485:C / Corp MSDS 1 (1), 911:B / FT-IR 1 (2), 1248:B / FT-IR 2 (3), 4517:C / RegBook 1 (2), 3079:E / Structure Index 1 , 488:C:4

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 9
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3335 UN3335
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sto
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Copper Catalysis 铜催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Copper Catalysis 铜催化剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organocopper - Organometallic Reagents
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Copper Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Cobalt
  1. Catalysts
  2. Copper
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂