Copper(I) Trifluoromethanesulfonate Benzene Complex 三氟甲烷磺酸铜(I)与苯的络合物
CAS 42152-46-5 MFCD00043300
化学结构图
SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[Cu+].[Cu+].c1ccccc1
化学属性
| Mol. Formula | (CF3SO3Cu)2 |
|---|---|
| Mol. Weight | 503 |
| Solubility | Soluble in hot benzene |
| TSCA | No |
| Melting Point | 160 °C (dec.)(lit.) |
| Density | 1.422 |
别名和识别编码
| Chemical Name | Copper(I) Trifluoromethanesulfonate Benzene Complex |
|---|---|
| MDL Number | MFCD00043300 |
| Synonym | Copper(I) triflate Copper(I) Triflate Benzene Complex 三氟甲烷磺酸铜与苯的络合物 三氟甲烷磺酸铜盐苯络合物 三氟甲烷磺酸铜苯络合物 三氟甲磺酸铜苯络合物 |
| CAS Number | 42152-46-5 |
| PubChem Substance ID | 2734754 |
| EC Number | 255-686-6 |
| Beilstein Registry Number | 14355676 |
| Chemical Name Translation | 三氟甲烷磺酸铜(I)与苯的络合物 |
| Reaxys-RN | 14355676 |
| InChIKey | DIMCZVTXAXZJCA-UHFFFAOYSA-L |
| InChI | InChI=1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
相关文献及参考
- The benzene complex has been utilized in combination with tri-n-butylphosphine in a catalyst system for the borylation of ɑß -enones with Bis(pinacolato)diboron, L16088: Tetrahedron Lett., 41, 6821 (2000).
安全信息
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H319 Causes serious eye irritation 严重刺激眼睛
- H228 Flammable solid 易燃固体
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P233 Keep container tightly closed. ?保持容器密闭。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P302+P352
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P332+P313
- P302+P352+P332+P313+P362+P364
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
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