Lithium aluminum deuteride 氘代氢化锂铝

CAS 14128-54-2 MFCD00044245

化学结构图

14128-54-2
SMILES: [2H][Al-]([2H])([2H])[2H].[Li+]

化学属性

Mol. FormulaLiAlD4
Mol. Weight42
Melting Point125 °C
Density0.736 g/mL at 25 °C
TSCANo
Flash Point<;-30 °F
RedoxReduction

别名和识别编码

Chemical NameLithium aluminum deuteride
Synonym Aluminum lithium hydride (LiAlD4) Lithium aluminum deuteride-d4 Lithium tetradeuterioaluminate Lithium aluminum deuteride Lithium aluminum deuteride (LiAlD4) Lithiumaluminiumdeuterid aluminium lithium deuteride Lithiumtetrahydridoaluminat-d4 Aluminate(1-), tetrahydro-d4-, Lithium, (T-4)- Lithium tetradeuteroaluminate Lithium tetrahydroaluminate-d4(1-) Lithium tetrahydro-d4-aluminate Lithium tetradeuteridoaluminate Lithium aluminium deuteride 氘代氢化锂铝 溶液 Lithium aluminum tetradeuteride Lithiumtetradeuteroaluminat LAD 氘代锂铝 Aluminum lithium hydride AlLiH4-d4 Deuterated LAH Lithium tetradeuteroaluminate(1-) lithium tetradeuteridoaluminate Lithium aluminum hydride-d4 氘代氢化锂铝 氘代锂铝
MDL NumberMFCD00044245
PubChem Substance ID24851582
EC Number237-980-6
CAS Number14128-54-2
Beilstein Registry Number2384789
Chemical Name Translation氘代氢化锂铝
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分类

  • {SA} Alphabetical Listings, I-L, Stable Isotopes
  • {uni_hamburg} no charge; isotope; 2fragments; ionic
  • {SNA} Alphabetical Listings, I-L, Stable Isotopes
  • {SNA} Alphabetical Listings, Alternative Energy, Deuterated Materials, I-L, Materials Science, Materials for Hydrogen Storage, Stable Isotopes

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany1
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Risk Statements
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R35 Causes severe burns 会导致严重灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Packing GroupI
UN Number 1410
Storage condition Moisture Sensitive
Hazard Codes F,C F,Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Stable Isotopes 稳定同位素
  3. Alphabetical Listings for Stable Isotope Labeled Products
  4. I-L - Alphabetical Listings
  1. Analytical & Chromatography 分析化学与色谱
  2. Stable Isotopes 稳定同位素
  3. Alphabetical Listings for Stable Isotope Labeled Products
  4. I-L - Alphabetical Listings

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