1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide 1-(3-二甲基氨基丙基)-3-乙基碳二亚胺
CAS 1892-57-5 MFCD00044916
化学结构图
SMILES: CCN=C=NCCCN(C)C
化学属性
| Mol. Formula | C8H17N3 |
|---|---|
| Mol. Weight | 155.24 |
| Refractive index | 1.4590 to 1.4630 |
| Density | 0.877 |
| Flash Point | >110°(230°F) |
| TSCA | Yes |
| Boiling Point | 197.7°C at 760 mmHg |
| Stability | 对空气和热敏感,易吸湿 |
别名和识别编码
| Chemical Name | 1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide |
|---|---|
| Reaxys-RN | 507429 |
| CAS Number | 1892-57-5 |
| PubChem Substance ID | 15908 |
| MDL Number | MFCD00044916 |
| Synonym | N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} {LY} N1-((Ethylimino)methylene)-N3,N3-dimethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} |
| EC Number | 217-579-2 |
| Beilstein Registry Number | 507429 |
| Alfabeta Name | DIMETHYLAMINOPROPYLETHYLCARBODIIMIDE NN3[]()----' |
| Chemical Name Translation | 1-(3-二甲基氨基丙基)-3-乙基碳二亚胺 |
| LabNetwork Molecule ID | LN00185247 |
| InChI | InChI=1S/C8H17N3/c1-4-9-8-10-6-5-7-11(2)3/h4-7H2,1-3H3 |
| Canonical SMILES | CN(C)CCCN=C=NCC |
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分类
- {SNA} Carbodiimides, Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Synthetic Reagents
产品应用
- An agent used to activate carboxylic acids for ester or amide formation.
相关文献及参考
- Free base form of 'Water-soluble' carbodiimide. For applications see following entry. In the presence of CuCl2, (E)- or (Z)-2-substituted 3-hydroxy-3-phenylpropionate esters can be dehydrated stereoselectively to the corresponding (E) or (Z)-cinnamates: Tetrahedron Lett., 40, 5019 (1999).
- Merck: 14,10328
安全信息
- P233 Keep container tightly closed. ?保持容器密闭。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
- P301+P312
- P301+P317
- P301+P330+P331
- P301+P330+P331+P310
- P302+P352
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P304+P341
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P317
- P333+P313
- P333+P317
- P342+P311
- P342+P316
- P361+P364
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403 Store in a well-ventilated place. 储存在通风良好的地方。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H311 Toxic in contact with skin 皮肤接触中毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
其他信息
- 敏感性:Air Sensitive
- 上游原料:乙醚 --> 二氯甲烷 --> 碳酸钾 --> 三乙胺 --> 4-甲苯磺酰氯 --> N,N-二甲基-1,3-二氨基丙烷 --> 异氰酸乙酯
- Alfa Aesar:1-（3-二甲基氨丙基）-3-乙基碳酰亚胺,98% 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide, 98%(1892-57-5)
- 1-(3-二甲基氨基丙基)-3-乙基碳二亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 B25057 1-（3-二甲基氨丙基）-3-乙基碳酰亚胺,98% 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide, 98% 5g 812元 2010/05/25 B25057 1-（3-二甲基氨丙基）-3-乙基碳酰亚胺,98% 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide, 98% 25g 2912元 2010/05/25 B25057 1-（3-二甲基氨丙基）-3-乙基碳酰亚胺,98% 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide, 98% 100g 10780元
- F:1-3-10
- MOL 文件:1892-57-5.mol
- Sigma Aldrich:1892-57-5(sigmaaldrich)
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