Di-Tert-Butylphenylphosphine 二叔丁基苯基膦

CAS 32673-25-9 MFCD00049096

化学结构图

32673-25-9
SMILES: CC(C)(C)P(C1C=CC=CC=1)C(C)(C)C

化学属性

Mol. FormulaC14H23P
Mol. Weight222.31
Density0.93(lit.)
Boiling Point128°C/10mmHg(lit.)
Refractive indexn20/D 1.5382
Appearance colorless liq.
Stabilityair sensitive

别名和识别编码

Chemical NameDi-Tert-Butylphenylphosphine
Synonym NSC 244300 二叔丁基苯基膦
MDL NumberMFCD00049096
PubChem Substance ID87561652
CAS Number32673-25-9
Reaxys-RN2802969
Chemical Name Translation二叔丁基苯基膦
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

安全信息

WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338
  • P422 Store contents under… 存储目录在…之下。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P337+P313
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P350
  • P370+P378
  • P337+P313
  • P302+P334+P352+P332+P313+P362+P364
Hazard statements
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R17 Spontaneously flammable in air 在空气中能够自燃
UN Number 2845
Hazard Class4.2

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Phosphines

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