4-Vinylbenzyl chloride 4-氯甲基苯乙烯

CAS 1592-20-7 MFCD00051362

化学结构图

1592-20-7
SMILES: C=Cc1ccc(CCl)cc1

化学属性

Mol. FormulaC9H9Cl
Mol. Weight152.62
Refractive indexn20/D 1.572(lit.)
Boiling Point228.9°C at 760 mmHg
Density1.083
Flash Point105°C

别名和识别编码

Chemical Name4-Vinylbenzyl chloride
Synonym 1-(Chloromethyl)-4-vinylbenzene {LY} 1-(Chloromethyl)-4-vinylbenzene {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Chloromethyl)-4-vinylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number1592-20-7
PubChem Substance ID74126
EC Number216-471-2
Beilstein Registry Number2204384
MDL NumberMFCD00051362
Reaxys-RN2204384
Chemical Name Translation4-氯甲基苯乙烯
InChIKeyZRZHXNCATOYMJH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195335
InChIInChI=1S/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2
Canonical SMILESC=CC1=CC=C(CCl)C=C1
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分类

  • {SNA} Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers, 材料科学
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • Materials Science, Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers

相关文献及参考

  • 1. Chem. Mater. 16 , 2648-2655, (2004)
  • 2. Chem. Mater. 16 , 2282-2286, (2004)
  • 3. Polymer Prepr. 43 , 140-141, (2002)
  • FT-IR 2 (2), 1705:D / Structure Index 1 , 181:E:3

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P312
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C <0°C <;0 {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitr
UN Number 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Packing GroupII
Hazard Class8

其他信息

  • Sigma Aldrich:1592-20-7(sigmaaldrich)
  • 上游原料:氢氧化钠 --> 二氯甲烷 --> 叔丁醇 --> 叔丁醇钾 --> 三氯化铝 --> 甲基叔丁基醚 --> 石脑油，原油 --> 氯甲基甲醚 --> 1,1,2,2-四氯乙烷 --> beta-溴代苯乙烷
  • 下游产品:4-(2-氰基乙基甲酰氨)苯基硼酸 --> 3-(2-氰基乙基甲酰氨)苯基硼酸 --> 4-(哌啶-1-羰基)苯基硼酸
  • 蒸气压:1 mm Hg ( 56.1 °C)
  • F:8-19
  • 存储注意事项:空气敏感;光敏感
  • 4-氯甲基苯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1792 4-(氯甲基)苯乙烯(含稳定剂TBC,ONP及2-硝基对甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) 250G 2260元 2014/06/02 C1792 4-(氯甲基)苯乙烯(含稳定剂TBC,ONP及2-硝基对甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) 25G 369元 2010/06/21 422525000 4-氯甲基苯乙烯 4-Vinylbenzyl chloride 90%, tech. 500 GR 4836元
  • Acros Organics:4-乙烯基苄氯 4-Vinylbenzyl chloride, tech., 90%(1592-20-7)
  • 蒸气密度:5.3 (vs air)
  • MOL 文件:1592-20-7.mol
  • TCI Shanghai:对氯甲基苯乙烯(含稳定剂对叔丁基邻苯二酚,邻硝基苯酚及邻硝基甲酚) 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol),>;90.0%(GC)(1592-20-7)
  • MSDS 信息:4-Chloromethyl styrene(1592-20-7).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  5. Acyclic - Alkenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  5. Acyclic - Alkenes
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Styrene and Functionalized Styrene Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Silicone Monomers

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