Bis(trimethylsilyl)carbodiimide 双(三甲基硅基)碳酰二亚胺

CAS 1000-70-0 MFCD00051538

化学结构图

1000-70-0
SMILES: C[Si](C)(C)N=C=N[Si](C)(C)C

化学属性

Mol. FormulaC7H18N2Si2
Mol. Weight186.40
Density0.821
Refractive index1.4320 to 1.4350
Boiling Point164 °C at 760 mmHg
Melting Point-23 °C
Flash Point41°C(lit.)
TSCAYes

别名和识别编码

Chemical NameBis(trimethylsilyl)carbodiimide
Synonym Bis(trimethylsilyl)carbodiimide {LY} Bis(trimethylsilyl)carbodiimide {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)carbodiimide {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00051538
CAS Number1000-70-0
EC Number213-673-2
Beilstein Registry Number2042082
PubChem Substance ID70473
Reaxys-RN2042082
Chemical Name Translation双(三甲基硅基)碳酰二亚胺
InChIKeyKSVMTHKYDGMXFJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01360977
InChIInChI=1S/C7H18N2Si2/c1-10(2,3)8-7-9-11(4,5)6/h1-6H3
Canonical SMILESC[Si](C)(C)N=C=N[Si](C)(C)C
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分类

  • {SNA} C-X Bond Formation (Non-Halogen), Chemical Synthesis, Others, Synthetic Reagents
  • {SNA} C-X Bond Formation (Non-Halogen), Chemical Synthesis, Other Non-Halogen Reagents for C-X Bond Formation, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25D
  • Short: III/35F
  • Can behave as a protected, highly-reactive cyanamide equivalent. Reacts with ketones in the presence of CsF, or KCN + 18-crown-6, to give N-cyanoimines. In the presence of TiCl4, quinones give N,N'-dicyanoquinodiimines: Angew. Chem. Int. Ed., 23, 447 (1984); Liebigs Ann. Chem., 142 (1986). Molecules of this type have found use as acceptor molecules in charge transfer complexes: J. Org. Chem., 57, 5726 (1992).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV1302500
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P303+P361+P353
  • P305+P351+P338
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 1993 UN 1993 3/PG 2
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage,
Hazard Codes 3
Hazard Class3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1728 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - ataxia
   Blood - hemorrhage
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(6),86,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1728 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - ataxia
   Blood - hemorrhage
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(6),86,1990

其他信息

  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • 敏感性:Moisture Sensitive
  • 急性毒性:口服-大鼠 LD50: 1728 毫克/公斤
  • Sigma Aldrich:1000-70-0(sigmaaldrich)
  • 图谱信息:二(三甲基硅基)碳酰二亚胺(1000-70-0)质谱(MS) 二(三甲基硅基)碳酰二亚胺(1000-70-0)核磁图( 1 HNMR) 二(三甲基硅基)碳酰二亚胺(1000-70-0)红外图谱(IR1) 二(三甲基硅基)碳酰二亚胺(1000-70-0)核磁图( 13 CNMR)
  • TSCA:Yes
  • 灭火剂:水,干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • Alfa Aesar:双(三甲基硅基)碳二亚胺,97% Bis(trimethylsilyl)carbodiimide, 97%(1000-70-0)
  • 二(三甲基硅基)碳酰二亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1368 双(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 25G 2910元 2011/04/16 B1368 双(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 5G 925元 2010/06/21 375130050 二(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 98% 5 GR 977元
  • F:10-21
  • 类别:有毒物质
  • TCI Shanghai:二(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide,>;98.0%(GC)(1000-70-0)
  • Acros Organics:双（三甲基硅基）碳二亚胺 Bis(trimethylsilyl)carbodiimide, 98%(1000-70-0)
  • MOL 文件:1000-70-0.mol
  • 二(三甲基硅基)碳酰二亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1368 双(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 25G 3220元 2014/06/02 B1368 双(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 5G 1030元 2010/06/21 375130050 二(三甲基硅基)碳酰二亚胺 Bis(trimethylsilyl)carbodiimide 98% 5 GR 977元
  • 可燃性危险特性:受热分解排放有毒氮氧化物烟雾

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Mitsunobu - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Others - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Others - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds

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