(3,5-Bis(trifluoromethyl)phenyl)boronic acid 3,5-双(三氟甲基)苯硼酸

CAS 73852-19-4 MFCD00051850

化学结构图

73852-19-4
SMILES: OB(O)c1cc(C(F)(F)F)cc(C(F)(F)F)c1

化学属性

Mol. FormulaC8H5BF6O2
Mol. Weight258
Melting Point219-226
TSCANo

别名和识别编码

Chemical Name(3,5-Bis(trifluoromethyl)phenyl)boronic acid
CAS Number73852-19-4
Alfabeta NameBISTRIFLUOROMETHYLBENZENEBORONICACID 35()-,
MDL NumberMFCD00051850
Synonym 3,5-双(三氟甲基)苯硼酸 3,5-Bis(trifluoromethyl)phenylboronic acid 3,5-二(三氟甲基)苯硼酸 3,5-双三氟甲基苯硼酸 3,5-Di(trifluoromethyl)benzeneboronic acid 3,5-双(三氟甲基)苯硼酸
Beilstein Registry Number7379990
PubChem Substance ID87564774
Reaxys-RN7379990
EC Number000-000-0
Chemical Name Translation3,5-双(三氟甲基)苯硼酸
InChIKeyBPTABBGLHGBJQR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115270
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • Has been used to protect a 1,3-diamine as the 2-aryl-1,3,2-diazaborinane, permitting selective reaction at a remote amine function: J. Am. Chem. Soc., 118, 1569 (1996).
  • Has been used to form chiral catalysts for use in enantioselective Diels-Alder reactions; see, for example: J. Org. Chem., 62, 3026 (1997) and references therein. See Appendix 5.
  • GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
GHS Symbol

系列性分类


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