Bis(dibenzylideneacetone)palladium 双(二亚芐基丙酮)钯
CAS 32005-36-0 MFCD00051942
化学结构图
SMILES: O=C(/C=C\c1ccccc1)/C=C\c1ccccc1.O=C(/C=C\c1ccccc1)/C=C\c1ccccc1.[Pd]
化学属性
| Melting Point | 150 |
|---|---|
| Solubility | Slightly soluble in CH2Cl2, CHCl3 and benzene |
| TSCA | No |
| Density | 1.422 |
| Mol. Formula | C34H28O2Pd |
| Mol. Weight | 575 |
| Appearance | purple pwdr. |
| Stability | air sensitive, moisture sensitive |
| Redox | Reduction |
别名和识别编码
| Chemical Name | Bis(dibenzylideneacetone)palladium |
|---|---|
| Alfabeta Name | BISDIBENZYLIDENEACETONEPALLADIUM () |
| Synonym | Palladium(0) bis(dibenzylideneacetone) |
| PubChem Substance ID | 6505921 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 双(二亚芐基丙酮)钯 |
| InChIKey | UKSZBOKPHAQOMP-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00222322 |
| MDL Number | MFCD00051942 |
| CAS Number | 32005-36-0 |
| InChI | InChI=1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+; |
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分类
- {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Homogeneous Pd Catalysts, Palladium
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
产品应用
- 加氢，异构化，羰基化，氧化，碳碳键构成反应。
- 用于合成烯丙基取代的环戊双烯。同源催化剂。温和条件下催化乙酸烯丙酯的烷化。把醇氧化成醛和酮的需氧氧化反应中用作环化硫脲的配体。
安全信息
GHS Symbol
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+P352+
- P302+P352+P312+P362+P364
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302+H312+H332
其他信息
- 不溶于水，微溶于二氯甲烷，氯仿和苯。
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