Fenvalerate 氰戊菊酯

CAS 51630-58-1 MFCD00055324

化学结构图

51630-58-1
SMILES: CC(C)C(C1=CC=C(Cl)C=C1)C(=O)OC(C#N)C1C=C(C=CC=1)OC1C=CC=CC=1

化学属性

Mol. FormulaC25H22ClNO3
Mol. Weight420
Density1.0
Refractive index1.5533
Stability对光敏感
Boiling Point300℃

别名和识别编码

Chemical NameFenvalerate
CAS Number51630-58-1
Synonym Sumipower 氰戊菊酯 S 5602 Aqmatrine Pydrin Sanmarton Furitrothion 速灭菊酯 Gold crest tribute ######## Belmark α-氰基-3-苯氧基苄基-α-(4-氯苯基)-3-甲基丁酸酯 alpha-Cyano-3-phenoxybenzyl-2-(4-chlorophenyl)-3-methylbutyrate Phenaxin cyano (3-phenoxybenzyl)-2-(4-chlorophenyl)-3-methylbutyrate Fenval Sumicidin 20E Cyano-3-phenoxyphenyl-methyl-4-chlor-α-(1-methylethyl)-benzolacetat Benzeneacetic acid, 4-chloro-α-(1-methylethyl)-, cyano(3-phenoxyphenyl)methyl ester cyano(3-phenoxybenzyl)methyl 2-(4-chlorophenyl)-3-methylbutyrate Fenkill 氰戊菊酯乳油 Fenkem Sumibac Phenvalerate Fenoxin Agrofen Cyano(3-phenoxyphenyl)methyl 4-chloro-α-(1-methylethyl)benzeneacetate 敌虫菊酯 OMS-2000 SD 43775 Ectrin WL 43775 Cyano(3-phenoxyphenyl)methyl 4-chloro-alpha-(1-methylethyl)benzeneacetate α-cyano-3-phenoxybenzyl 2-(4-chlorophenyl)-3-methylbutyrate Insectral Sumifleece 腈苯苯醚菊酯 α-氰基-3-苯氧基苄基-α-(4-氯苯基)-3-甲基丁酸酯 Sumicidin α-Cyano-3-phenoxybenzyl 2-(4-chlorophenyl)isovalerate Evercide 2362 Fenaxin Cyan(3-phenoxybenzyl)-2-(4-chlorphenyl)-3-methylbutyrat 速灭杀丁 Sumitick Phenoxin Cyan(3-phenoxybenzyl)methyl 2-(4-chlorphenyl)-3-methylbutyrat Tribute Fenvalerate Sumifly SCS alpha-Cyano-3-phenoxybenzyl 2-(4-chlorophenyl)isovalerate
MDL NumberMFCD00055324
Beilstein Registry Number2025982
EC Number257-326-3
Chemical Name Translation氰戊菊酯
Wiswesser Line Notation1Y1&YR DG&VOYCN&R COR
PubChem Substance ID329799681
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分类

  • {Chemicalbook} 农药: 杀虫(螨)剂: 拟除虫菊酯杀虫剂
  • {SNA} Bioactive Small Molecule Alphabetical Index, Calcium Antagonists, F, Intracellular Calcium Signaling, Kinase/Phosphatase Biology, Protein Phosphatase 2B (Calcineurin/PP2B), Serine/Threonine Kinase Biology, Serine/Threonine Phosphatase Inhibitors, 生物活性小分子, 细胞信号转导和神经科学, 细胞生物学
  • {SNA} Acaricides, Analytical Standards, Analytical/Chromatography, Bioactive Small Molecules, Calcium Antagonists, Cell Biology, Cell Signaling and Neuroscience, Chromatography,
  • {SNA} Additional Standards, Analytical Standards, E-G, EPA, Endocrine Disruptors (Draft),
  • {SNA} Additional Standards,

产品应用

  • 该品为广谱高效杀虫剂,作用迅速,击倒力强,以角杀为主,也有胃毒作用,可防治多种棉花害虫,如棉铃虫,棉蚜等,广泛用于防治烟草、大豆、玉米、果树、蔬菜的害虫,也可用于防治家畜和仓储等方面的害虫。
  • 校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。

相关文献及参考

  • [2]. A R Reilein, et al. Regulation of Organelle Movement in Melanophores by Protein Kinase A (PKA), Protein Kinase C (PKC), and Protein Phosphatase 2A (PP2A). J Cell Biol. 1998 Aug 10;142(3):803-13.
  • Choudhary, S., et al.: J. Industrial Poll. Cont., 25, 145 (2009),
  • Merck: 14,4010
  • Sharma, R., et al.: Environ. Ecol., 27, 1481 (2009),
  • Short: EINECS2
  • Short: II/20B5
  • Tang, J., et al.: Pest Man. Sci., 66, 121 (2010),
  • [1]. E Enan, et al. Specific Inhibition of Calcineurin by Type II Synthetic Pyrethroid Insecticides. Biochem Pharmacol. 1992 Apr 15;43(8):1777-84.
  • [1]. E Enan, et al. Specific Inhibition of Calcineurin by Type II Synthetic Pyrethroid Insecticides. Biochem Pharmacol. 1992 Apr 15;43(8):1777-84.
  • [2]. A R Reilein, et al. Regulation of Organelle Movement in Melanophores by Protein Kinase A (PKA), Protein Kinase C (PKC), and Protein Phosphatase 2A (PP2A). J Cell Biol. 1998 Aug 10;142(3):803-13.

安全信息

RTECSCY1576350
WGK Germany3
Hazard Codes T,N
Signal word Danger Warning
GHS Symbol
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
  • R57 Toxic to bees 对蜜蜂有毒
Precautionary statements
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Packing GroupIII
UN Number 2811
Storage condition 常温下避光、干燥处保存。 储存温度2-8℃
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,388,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 185 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   5,278,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - domestic
DOSE/DURATION           : >1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A207,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 70200 ug/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - excitement
   Behavioral - ataxia
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 21,215,1987

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{h

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 222,149,1989

TYPE OF TEST            : Morphological transformation
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 3750 mg/kg/10W (Intermittent)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   61,218,1988

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 2 mg/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 4,72,1989

TYPE OF TEST            : Micronuc

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 222,149,1989

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 300 mg/kg/24H (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 222,149,1989

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 1050 mg/kg/3W (Continuous)
REFERENCE :

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 100 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 222,149,1989

其他信息

  • 20℃的蒸汽压力为3.1*10-8kpa,25℃的蒸气压为3.7*10-8kpa,20℃的溶解度:水<1mg/L,己烷77g/L、丙酮、乙醇、氯仿、二甲苯、环己酮均大于450g/L。热稳定性好,75℃防治100h式无明显分解;在酸性条件下稳定,在ph>8的碱性介质中不稳定。
  • 20℃的蒸汽压力为3.1*10-8kpa,25℃的蒸气压为3.7*10-8kpa,20℃的溶解度:水<1mg/L,己烷77g/L、丙酮、乙醇、氯仿、二甲苯、环己酮均大于450g/L。热稳定性好,75℃防治100h式无明显分解;在酸性条件下稳定,在ph>10的碱性介质中不稳定。
  • HazardClass:6.1(b)
  • 20℃的蒸汽压力为3.1*10-8kpa,25℃的蒸气压为3.7*10-8kpa,20℃的溶解度:水<1mg/L,己烷77g/L、丙酮、乙醇、氯仿、二甲苯、环己酮均大于450g/L。热稳定性好,75℃防治100h式无明显分解;在酸性条件下稳定,在ph>11的碱性介质中不稳定。

系列性分类


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