6,6'-Dimethyl-2,2'-bipyridine 6,6‘-二甲基-2,2’-联吡啶

CAS 4411-80-7 MFCD00059776

化学结构图

4411-80-7
SMILES: Cc1cccc(-c2cccc(C)n2)n1

化学属性

Mol. FormulaC12H12N2
Mol. Weight184.24
Density1.422
Melting Point93-95°C
Boiling Point278.6°C at 760 mmHg

别名和识别编码

Chemical Name6,6'-Dimethyl-2,2'-bipyridine
CAS Number4411-80-7
EC Number224-566-5
Beilstein Registry Number128972
MDL NumberMFCD00059776
PubChem Substance ID20445
Synonym 6,6'-Dimethyl-2,2'-bipyridyl {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6,6'-Dimethyl-2,2'-bipyridyl {} {} {} {} {} {} {} {} {} {} {} {
Reaxys-RN128972
Chemical Name Translation6,6‘-二甲基-2,2’-联吡啶
InChIKeyOHJPGUSXUGHOGE-UHFFFAOYSA-N
Wiswesser Line NotationT6NJ F1 B- BT6NJ F1
LabNetwork Molecule IDLN00220966
Canonical SMILESCC1=NC(C2=CC=CC(C)=N2)=CC=C1
InChIInChI=1S/C12H12N2/c1-9-5-3-7-11(13-9)12-8-4-6-10(2)14-12/h3-8H,1-2H3
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分类

  • {SNA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSDW1767000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 190 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXIA6 Toxicon.  (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW,
   UK)  V.1-    1962-  Volume(issue)/page/year: 23,815,1985

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:6,6'二甲基-2，2'-联吡啶 6,6'-Bi-2-picoline,>;98.0%(GC)(T)(4411-80-7)
  • 6,6'-二甲基-2,2'-联吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0842 6,6'二-2-甲基吡啶 6,6'-Dimethyl-2,2'-bipyridyl 5G 3950元 2014/06/02 B0842 6,6'二-2-甲基吡啶 6,6'-Dimethyl-2,2'-bipyridyl 1G 1140元 2014/06/02 B0842 6,6'二-2-甲基吡啶 6,6'-Dimethyl-2,2'-bipyridyl 100MG 275元
  • 上游原料:氢氧化钠 --> 二氯甲烷 --> 硫酸镁 --> 锌粉 --> 三苯基膦 --> 甲酸钠 --> 苄基三乙基氯化铵 --> 二乙二醇二甲醚 --> 10%钯碳 --> 叔丁醇钠 --> 醋酸镍(四水) --> 双(三苯基膦)氯化镍 --> 2-溴-6-甲基吡啶 --> 四乙基碘化铵
  • 图谱信息:6,6'-二甲基-2,2'-联吡啶(4411-80-7)核磁图( 13 CNMR) 6,6'-二甲基-2,2'-联吡啶(4411-80-7)核磁图( 1 HNMR) 6,6'-二甲基-2,2'-联吡啶(4411-80-7)红外图谱(IR1) 6,6'-二甲基-2,2'-联吡啶(4411-80-7)质谱(MS)
  • MOL 文件:4411-80-7.mol

系列性分类

  1. C12 - Pyridines
  1. C6 to C7 - Pyridines

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