(+)-Methyl (R)-2-Chloropropionate (+)-(R)-2-氯丙酸甲酯

CAS 77287-29-7 MFCD00062940

化学结构图

77287-29-7
SMILES: COC(=O)[C@@H](C)Cl

化学属性

Mol. FormulaC4H7ClO2
Mol. Weight122.55
Refractive index1.4160 to 1.4200
Boiling Point134°C(lit.)
Density1.152
Flash Point37°C(lit.)

别名和识别编码

Chemical Name(+)-Methyl (R)-2-Chloropropionate
Synonym (+)-(R)-2-氯丙酸甲酯 (R)-(+)-2-氯丙酸甲酯
CAS Number77287-29-7
PubChem Substance ID87566626
EC Number278-658-5
Beilstein Registry Number2,248
MDL NumberMFCD00062940
Chemical Name Translation(+)-(R)-2-氯丙酸甲酯
Reaxys-RN1720590
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 1227:D / Corp MSDS 1 (2), 2319:B / FT-NMR 1 (1), 1014:A / RegBook 1 (1), 737:G / Sigma FT-IR 1 (1), 1379:B / Structure Index 1 , 113:D:5 / Vapor Phase 3 , 705:B
  • Beil. 2 ,H,248

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P303+P361+P353
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class3
UN Number 2933
Packing GroupIII
Warnings 危化品目录(2015) 危险化学品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Esters - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Esters - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块

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