(-)-Camphene (-)-莰烯

CAS 5794-04-7 MFCD00064161

化学结构图

5794-04-7
SMILES: C=C1[C@@H]2CC[C@@H](C2)C1(C)C

化学属性

Mol. FormulaC10H16
Mol. Weight136
Boiling Point157.5-158.5 °C(lit.)
Density0.84 g/mL at 25 °C(lit.)
Melting Point36-38 °C (lit.)

别名和识别编码

Chemical Name(-)-Camphene
Synonym (-)-Camphene (-)-camphene (1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane (1S)-2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane {} {} {} {uni_hamburg}
CAS Number5794-04-7
PubChem Substance ID440966
EC Number227-337-8
Beilstein Registry Number2204256
MDL NumberMFCD00064161
Chemical Name Translation(-)-莰烯
Reaxys-RN1903765
Merck Number1730
InChIInChI=1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m1/s1
LabNetwork Molecule IDLN04694328
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分类

  • {SNA} Alkenes, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 5ring; 6ring; chiral; 1fragment
  • Alkenes, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

相关文献及参考

  • Beil. 5 ,IV,461
  • Corp MSDS 1 (1), 671:C / FT-NMR 1 (1), 78:A / RegBook 1 (1), 49:D / Sax 6 , 625 / Structure Index 1 , 6:B:7
  • Merck ,1737
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H228 Flammable solid 易燃固体
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Risk Statements
  • R10 Flammable 易燃
Hazard Class4.1
RTECSEX1055000
UN Number 1325
Packing GroupII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alkenes - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alkenes - Organic Building Blocks