(R)-(-)-2-Butanol (R)-丁烷-2-醇

CAS 14898-79-4 MFCD00064280

化学结构图

14898-79-4
SMILES: CC[C@@H](C)O

化学属性

Mol. FormulaC2H5CH(OH)CH3
Mol. Weight74
Refractive index1.3960 to 1.3980
Autoignition Point761 °F
Vapor Density2.6 (vs air)
Boiling Point97-100
Vapor Pressure12.5 mmHg ( 20 °C)
Density0.807
Flash Point24°C(lit.)
TSCAYes
Melting Point-114 ºC
Solubility125 G/L (20 ºC)

别名和识别编码

Chemical Name(R)-(-)-2-Butanol
Synonym (R)-(-)-2-butanol (R)-(-)-sec-Butyl alcohol (R)-(-)-sec-Butyl alcohol (R)-(-)-仲丁基醇 (R)-2-Butanol (R)-Butanol-2 (R)-butan-2-ol (R)-butanol-(2) -(−)-sec-Butyl alcohol 2-Butanol, (R)- R(-)-2-butanol R-(-)-sec-Butanol R-(-)-sec-Butyl alcohol l-2-Butanol
Beilstein Registry Number1718764
PubChem Substance ID87563889
EC Number238-967-8
MDL NumberMFCD00064280
CAS Number14898-79-4
Merck Number1541
Reaxys-RN1718764
Chemical Name Translation(R)-丁烷-2-醇
LabNetwork Molecule IDLN00241246
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分类

  • {SNA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {uni_hamburg} no charge; alcohol; chiral; 1fragment

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/8G Title: Densities of Alcohols Author: Frenkel, M.; Hong, X.; Wilhoit, R.C.; Hall, K.R. Editor: Hall, K.R.; Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8G Year: 2000 Keyword: organic compounds; density; liquids ISBN: 3-540-66233-2 ISBN: 978-3-540-66233-4 Internet Resource: DOI:10.1007/b75928 RefComment: XI, 413 pages, with CD-ROM, Hardcover

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P304+
  • P305+P351+P338
  • P308+P313
  • P337+P313
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupII
UN Number 1120
Risk Statements
  • R10 Flammable 易燃
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
Hazard Codes 3
Hazard Class3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Acid Halides 酰卤
  1. Materials Science 材料科学
  2. Building Blocks for Liquid Crystals