trans-Stilbene 反式-1,2-二苯乙烯
CAS 103-30-0 MFCD00064300
化学结构图
SMILES: C(=C/c1ccccc1)\c1ccccc1
化学属性
| Mol. Formula | C14 H12 |
|---|---|
| Mol. Weight | 180.25 |
| Density | 0.97 g/mL at 25 °C(lit.) |
| Boiling Point | 307°C(lit.) |
| Melting Point | 123.0 to 126.0 deg-C |
| TSCA | Yes |
| Flash Point | 305-307°C |
| Appearance | 无色针状结晶。熔点124-125℃，沸点305℃（9.5989kPa），166-167℃（1.6kPa），相对密度1.0281，折射率1.6264（17℃）。不溶于水，微溶于乙醇，可溶于醚和苯。能随水蒸气挥发。 |
别名和识别编码
| Chemical Name | trans-Stilbene |
|---|---|
| MDL Number | MFCD00064300 |
| CAS Number | 103-30-0 |
| Synonym | (1,2-Ethendiyl)-1,1-bisbenzene (1,2-Ethenediyl)-1,1-bisbenzene, (E)- (E)-1,2-Diphenylethylene (E)-1,2-diphenylethene (E)-Stilbene (e)-1,1’-( (e)-stilbene 1,1'-(1E)-1,2-Ethenediylbis[benzene] 1,2-Diphenylethene 1,2-Diphenylethylene (tr 1,2-二苯乙烯 1,trans-2-Diphenylethene 1,trans-2-Diphenylethene trans stilbene trans-1,1'-(1,2-Ethe trans-1,2-diphenyl-ethene trans-1,2-diphenylethylene trans-a,ß-Diphenylethylene trans-stilbe trans-α, β-Diphenylethylene trans-α,β-diphenylethylene Benzene, 1,1'-(1E)-1,2-ethenediylbis- Benzene, 1,1'-(1,2-ethenediyl)bis-, (E)- C< |
| EC Number | 203-098-5 |
| Beilstein Registry Number | 5(2)537 |
| PubChem Substance ID | 87575706 |
| Merck Number | 8817 |
| Reaxys-RN | 1616740 |
| Chemical Name Translation | 反式-1,2-二苯乙烯 |
| Wiswesser Line Notation | R1U1R -T |
| LabNetwork Molecule ID | LN01072850 |
| InChI | InChI=1S/C14H12/c1-3-7-13(8-4-1)11-12-14-9-5-2-6-10-14/h1-12H/b12-11+ |
| Canonical SMILES | C1(/C=C/C2=CC=CC=C2)=CC=CC=C1 |
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分类
- {SNA} Bioactive Small Molecules, Light-Emitting Dopants and Fluorescent Dyes, Materials Science, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, S, 细胞生物学
- {SNA} Bioactive Small Molecule Alphabetical Index, Light-Emitting Dopants and Fluorescent Dyes, Materials Science, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, S, 生物活性小分子, 细胞生物学
- {SNA} Light-Emitting Dopants and Fluorescent Dyes, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, 材料科学
- {SNA} Light-Emitting Dopants and Fluorescent Dyes, Materials Science,
相关文献及参考
- Reaction with NBS in aqueous DMSO gives the bromohydrin: Org. Synth. Coll., 6, 184 (1988). Oxidation to benzil can be effected with iodine in DMSO: Synthesis, 131 (1991).
- Short: II/25D
- Asymmetric dihydroxylation with N-methylmorpholine N-oxide, in the presence of osmium tetroxide and dihyroquinidine 4-chlorobenzoate, has been described: Org. Synth. Coll., 9, 383 (1998).
- Short: II/27C
安全信息
GHS Symbol
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P312+P330
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 6500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : YHHPAL Yaoxue Xuebao. Acta Pharmaceutica Sinica. Pharmaceutical Journal. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.1- 1953- Suspended 1966-78. Volume(issue)/page/year: 14,227,1979
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 920 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : YHHPAL Yaoxue Xuebao. Acta Pharmaceutica Sinica. Pharmaceutical Journal. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.1- 1953- Suspended 1966-78. Volume(issue)/page/year: 14,227,1979
其他信息
- Sigma Aldrich:103-30-0(sigmaaldrich)
- 下游产品:二苯基乙炔 --> 氢胺
- 用途一:有机合成原料，可制二苯乙炔，作闪烁试剂，也用于荧光增白剂及染料的合成。
- MOL 文件:103-30-0.mol
- Alfa Aesar:反-1,2-二苯乙烯,,98% trans-Stilbene, 98%(103-30-0)
- 反式-1，2二苯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30171380 反式菧 25g 200元 2011/04/16 S0090 反-均二苯乙烯 trans-Stilbene 500G 2080元 2011/04/16 S0090 反-均二苯乙烯 trans-Stilbene 25G 270元
- TCI Shanghai:反-1,2-二苯基乙烯 trans-Stilbene,>;98.0%(GC)(103-30-0)
- 方法一:由安息香（即二苯基羟基乙酮或称苯偶姻，[579-44-2]）在锌汞齐存在下脱水而得。先制备锌汞齐，将其加入乙醇及安息香中，然后在搅拌下滴加盐酸，保持温度15℃。2h加完，再继续搅拌2h，加入冷水，然后滤出沉淀，用热乙醇提取，冷却，结晶，再用乙醇重结晶而得成品。
- 图谱信息:反式-1，2二苯乙烯(103-30-0)红外图谱(IR2) 反式-1，2二苯乙烯(103-30-0)红外图谱(IR1) 反式-1，2二苯乙烯(103-30-0)核磁图( 1 HNMR) 反式-1，2二苯乙烯(103-30-0)质谱(MS) 反式-1，2二苯乙烯(103-30-0)Raman光谱 反式-1，2二苯乙烯(103-30-0)核磁图( 13 CNMR)
- Acros Organics:反式-1，2-二苯乙烯 trans-Stilbene, 96%(103-30-0)
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