L-Phenylglycine L-苯甘氨酸

CAS 2935-35-5 MFCD00064403

化学结构图

2935-35-5
SMILES: N[C@H](C(=O)O)c1ccccc1

化学属性

Mol. FormulaC8H9NO2
Mol. Weight151.16
Density1.246
Melting Point>300 °C
TSCAYes
Refractive index158 ° (C=1, 1mol/L HCl)
Boiling Point288.7°C at 760 mmHg

别名和识别编码

Chemical NameH-Phg-OH
MDL NumberMFCD00064403
CAS Number2935-35-5
EC Number220-909-8
Beilstein Registry Number14,459
Synonym H-Phg-OH {LY} H-Phg-OH L-Phg amino acid L-phenylglycine {} {LY} H-Phg-OH {} {} {LY} H-Phg-OH {} {} {} {LY} H-Phg-OH {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Phg-OH {} {} {} {} {} {} {} {} {} {} {}
Merck Number7291
PubChem Substance ID99291
Reaxys-RN2208675
Chemical Name TranslationL-苯甘氨酸
LabNetwork Molecule IDLN00239349
InChIInChI=1S/C8H9NO2/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5,7H,9H2,(H,10,11)/t7-/m0/s1
Canonical SMILESN[C@H](C(O)=O)C1=CC=CC=C1
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Peptide Chemistry, Phenylglycine Derivatives, Unnatural Amino Acids & Derivatives
  • {SNA} Chemical Biology, Chemical Synthesis, Peptide Chemistry, Phenylglycine Derivatives, Unnatural Amino Acid Derivatives

产品应用

  • 用于制造氨苄青霉素和头孢氨苄等药物。

相关文献及参考

  • Merck: 14,7291
  • Merck: 14,7291 Beilstein:14,459

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C {LY} 2-8°C Store at RT. Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • TCI Shanghai:L-2-苯基甘氨酸 L-2-Phenylglycine,>;97.0%(T)(2935-35-5)
  • L-苯甘氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp620065 L-苯甘氨酸 25g 106.8元 2011/04/16 P1288 L-2-苯甘氨酸 L-2-Phenylglycine 500G 2730元 2011/04/16 P1288 L-2-苯甘氨酸 L-2-Phenylglycine 25G 404元
  • 比旋光度:157 ° (c=2, 2N HCl)
  • MSDS 信息:L(+)-alpha-Phenylglycine(2935-35-5).msds
  • Alfa Aesar:L-(+)-2-苯基甘氨酸,98+% L-(+)-2-Phenylglycine, 98+%(2935-35-5)
  • 图谱信息:L-苯甘氨酸(2935-35-5)红外图谱(IR1) L-苯甘氨酸(2935-35-5)质谱(MS) L-苯甘氨酸(2935-35-5)红外图谱(IR2) L-苯甘氨酸(2935-35-5)Raman光谱
  • Sigma Aldrich:2935-35-5(sigmaaldrich)
  • 用途二:用于医药的中间体。
  • 外观性质:白色或几乎白色结晶性粉末。熔点：300 ºC [α]20D 157° (c=2, 2N HCl)
  • 用途三:用于制造氨苄青霉素和头孢氨苄等药物。
  • 上游原料:氰化钠 --> 苯甲醛 --> 2-羟基苯甲醛 --> DL-10-樟脑磺酸
  • MOL 文件:2935-35-5.mol
  • Acros Organics:L-alpha-苯基甘氨酸 L(+)-alpha-Phenylglycine, 99%(2935-35-5)
  • 用途一:用于制造氨苄青霉素和头孢氨苄等药物
  • 海关编码:29224995

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Phenylglycine Derivatives - Unnatural Amino Acid Derivatives