Sulfuric Acid 硫酸(易制毒)

CAS 7664-93-9 MFCD00064589

化学结构图

7664-93-9
SMILES: O=S(=O)(O)O

化学属性

Mol. FormulaH2SO4
Mol. Weight98.08
Boiling Point~290 °C(lit.)
Density1.840 g/mL at 25 °C(lit.)
Vapor Density<;0.3 (25 °C, vs air)
Vapor Pressure1 mmHg ( 146 °C)
TSCAYes
Stability对湿度敏感
Melting Point10°C

别名和识别编码

Chemical NameSulfuric Acid
CAS Number7664-93-9
PubChem Substance ID1118
EC Number231-639-5
Beilstein Registry Number2037554
MDL NumberMFCD00064589
Synonym Acide sulfurique Acido solforico BOV Battery acid Dihydrogen sulfate Dipping acid Electrolyte acid Mattling acid Oil of vitriol Schwefelsaeureloesungen Sulfuric acid Sulphuric acid Vitriol Brown Oil Zwavelzuuroplossingen sulfuric acid 硫酸 硫酸 溶液
Merck Number14,8974
Chemical Name Translation硫酸(易制毒)
Wiswesser Line NotationH2 S-O4
InChIInChI=1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)
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分类

  • {SNA} Acid Solutions, Acid solutions available in VOLPAC containers (5 and 10 L), By Reference Material, Most common compounds for volumetric titration, Reference Material Sodium carbonate, Solution containers 5 L / 10 L (VOLPAC), Sulfuric acid solution, Titration, Volumetric Solutions, 分析/色谱, 分析试剂
  • {SNA} Acid Solutions, Most common compounds for volumetric titration, Sulfuric acid solution, Titration, Volumetric Solutions, 分析/色谱, 分析试剂
  • {SNA} Acid Solutions, Acid solutions available in VOLPAC containers (5 and 10 L), Analytical Reagents, Analytical/Chromatography, By Reference Material, Most common compounds for volumetri

产品应用

  • 为分析和实验室广泛使用的试剂。钡、锶和铅的沉淀剂,有机分析及合成中吸收水份,磺化作用,缩合作用与硝酸混合用于硝化作用。MOS级适用于电子工业半导体集成电路生产之用。

相关文献及参考

  • Merck: 14,8974

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
RTECSWS5600000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P317
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P354+P338
  • P307+P311
  • P308+P316
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
UN Number UN2796
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
Storage condition 密封干燥保存,避免水分及有机物进入 室温储存
Restrict 易制毒 {} 易制毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projec

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 135 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M.,
   Springfield, IL, C.C. Thomas, 1970  Volume(issue)/page/year: 2,73,1970

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 510 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,107,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 18 mg/m3
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   MELAAD Medicina del Lavoro.  Industrial Medicine.  (Via S. Barnaba, 8, 20122
   Milan, Italy) V.16-    1925-  Volume(issue)/page/year: 45,590,1954

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 4 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 225,55,1989

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 20 mg/m3/7H
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   JEHSDH Journal of Environmental Science and Health, Part C: Environmental
   Health Sciences. New York, NY)  V.13, 1978-79.  Volume(issue)/page/year:
   13,251,1979

其他信息

  • 1.将本品垂直放于1升的容量瓶上。
  • 每瓶安瓿可稀释成一升的滴定液
  • 2.用附带的小工具从上至下刺破薄膜,使浓缩液流入容量瓶中
  • 使用方法:
  • 无气味,强腐蚀性。能与水、醇任意混和,并放出大量热而猛烈溅开,宜将酸渐渐放入水中。暴露空气中迅速吸收水分,也能夺取有机物如糖、木等中的水分子而碳化。
  • 注:本包装为浓缩液,是用来稀释成1升的分析滴定液。稀释后的浓度即为标签上所示浓度。(在允许的不确定度区间之内)
  • 3.取适量的蒸馏水润洗本产品的容器,并使之流入到容量瓶中,直至加到一升容量瓶的刻度处

系列性分类


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