5-(4-Dimethylaminobenzylidene)rhodanine 5-(4-二甲氨基亚苄基)罗丹宁

CAS 536-17-4 MFCD00064857

化学结构图

536-17-4
SMILES: CN(C)c1ccc(/C=C2/SC(=S)NC2=O)cc1

化学属性

Mol. FormulaC12H12N2OS2
Mol. Weight264
Melting Point285-288
TSCAYes
Density1.36

别名和识别编码

Chemical Name5-(4-Dimethylaminobenzylidene)rhodanine
MDL NumberMFCD04969049
PubChem Substance ID87567291
Beilstein Registry Number27,433
CAS Number536-17-4
EC Number208-625-2
Reaxys-RN6723919
Merck Number3231
Synonym 5-(p-Dimethylaminobenzoylidene)rhodanine 5-(p-dimethylaminobenzal)rhodanine 对二甲氨基苄叉罗丹宁 p-Dimethylaminobenzalrhodanine 5-(P-DIMETHYLAMINOBENZYLIDENE)-RHODAMINE 5-(4-DIMETHYLAMINOBENZYLIDENE)RHODANINE 5-[4-(dimethylamino)phenyl]methylene-2-thioxo-4-Thiazolidinone p-Dimethylaminobenzylidene rhodamine 二甲基胺亚苄基罗丹宁 4-二甲基氨基苯亚甲基罗丹宁;5-(对二甲氨基亚苄基)罗丹宁 對二甲胺苯亞甲若丹林 5-[4-(二甲基氨基)苯基]亚甲基-2-硫代-4-噻唑烷酮 5-[[4-(dimethylamino)phenyl]methylene]-2-thioxo-4-thiazolidinon 试银灵 5-［4-（二甲基氨基）苯基］亚甲基-2-硫代-4-噻唑烷酮 4-Dimethylaminobenzalrhodanine {Chemicalb 对二甲氨基亚苄罗丹宁 5-(4-二甲氨
Chemical Name Translation5-(4-二甲氨基亚苄基)罗丹宁
Wiswesser Line NotationT5SYMV EHJ BUS E1U1R DN1&1
LabNetwork Molecule IDLN00195906
InChIInChI=1S/C12H12N2OS2/c1-14(2)9-5-3-8(4-6-9)7-10-11(15)13-12(16)17-10/h3-7H,1-2H3,(H,13,15,16)/b10-7+
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分类

  • {SNA} Building Blocks, C12 to C20+, Chemical Synthesis, Heterocyclic Building Blocks, Thiazoles
  • Alkaloids, Amines, Amino Acids, Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents HPLC, Derivatization Reagents TLC, Hydrazines, Indoles, Metals, precious, Peroxides, Proteins & Peptides, TLC Reagents, D-F, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application), UV-VIS
  • {SA} Alkaloids, Amines, Amino Acids, Analytical Reagents, Analytical/Chromatograp

产品应用

  • 用于检测Ag、Au、 Cu、Hg、Pd、Pt、生物碱(alkaloids)、安替比林、尿蓝母(indican)、硫铵安类药剂和尿胆素原(urobilinogen)
  • 主要是测定银、钯和汞的试剂1,2；也用于检测金3； 用于光度法测定放射自显影4。
  • 参考文献：
  • 1. G.H. Ayres et al. Anal. Chim. Acta 24, 241, (1961)
  • 2. G. Jangg Fresenius J. Anal. Chem. 183, 255, (1961)
  • 3. L.E. Lichtenstein Anal. Chem. 47, 465, (1975)
  • 4. J.W. Ludlow et al. Anal. Biochem. 154, 104, (1986) abstract

相关文献及参考

  • Merck:14,3231 Beilstein:27,433
  • Merck:14,3231
  • Reagent for detection of Ag, Hg, Cu, Au, Pt and Pd ions.

安全信息

RTECSVI8090000
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
GHS Symbol 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,11,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD603-561

其他信息

  • 检测方法:HPLC,NMR
  • Acros Organics:5-(对二甲氨基亚苄基)罗丹宁/试银灵 5-(4-Dimethylaminobenzylidene)rhodanine, 99%(536-17-4)
  • Sigma Aldrich:536-17-4(sigmaaldrich)
  • 图谱信息:试银灵 (536-17-4)红外图谱(IR2) 试银灵 (536-17-4)红外图谱(IR1) 试银灵 (536-17-4)质谱(MS)
  • 用途一:用于检测Ag、Au、 Cu、Hg、Pd、Pt、生物碱(alkaloids)、安替比林、尿蓝母(indican)、硫铵安类药剂和尿胆素原(urobilinogen) 主要是测定银、钯和汞的试剂1,2；也用于检测金3； 用于光度法测定放射自显影4。参考文献：1. G.H. Ayres et al. Anal. Chim. Acta 24, 241, (1961)2. G. Jangg Fresenius J. Anal. Chem. 183, 255, (1961)3. L.E. Lichtenstein Anal. Chem. 47, 465, (1975)4. J.W. Ludlow et al. Anal. Biochem. 154, 104, (1986) abstract
  • Alfa Aesar:5-(4-二甲基氨基苯亚甲基)绕丹宁,98% 5-(4-Dimethylaminobenzylidene)rhodanine 98%(536-17-4)
  • MOL 文件:536-17-4.mol
  • TCI Shanghai:5-[4-(二甲基氨基)苯基]亚甲基-2-硫代-4-噻唑烷酮 4-Dimethylaminobenzylidenerhodanine,>;98.0%(LC)(T)(536-17-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazines 噻嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents TLC - Derivatization Reagents
  5. TLC Visualization Reagents (by application) - Derivatization Reagents TLC
  6. Alkaloids - TLC Visualization Reagents (by application)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  5. C12 to C20+ - Thiazoles
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Aldehydes/Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Alkaloids
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Halogens
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Hydrazines
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Metal Ions
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Osazones
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Phosphorylated Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Aldehydes/Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Alkaloids
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Halogens
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Hydrazines
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Metal Ions
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Osazones
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Phosphorylated Compounds

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