Dehydroascorbic acid 去氢抗坏血酸

CAS 490-83-5 MFCD00066467

化学结构图

490-83-5
SMILES: O=C1OC(C(O)CO)C(=O)C1=O

化学属性

Mol. FormulaC₆H₆O₆
Mol. Weight174.11
Melting Point>175°C (dec.)
Boiling Point
Flash Point-

别名和识别编码

Chemical NameDehydroascorbic acid
CAS Number490-83-5
Synonym (5R)-5β-[(S)-1,2-Dihydroxyethyl]tetrahydrofuran-2,3,4-trione 5-(1,2-dihydroxyethyl)oxolane-2,3,4-trione Acid, Dehydroascorbic BIS-DEHYDRO-L-ASCORBIC ACID BIS-DHA Bis(dehydro-L-ascorbic acid) Bis(dehydro-L-ascorbic acid) Bis-DHA DHA Bis-DHA DEHYDRO-L(+)-ASCORBIC ACID, DIMER DEHYDRO-L-ASCORBIC ACID DEHYDROASCORBIC ACID DEHYDROASCORBIC ACID(RG) DHA Dehydro-L-ascorbic Acid Dehydroascorbic Acid Dehydroascorbic acid L-(+)-Dehydroascorbic Acid (1.24728) L-ASCORBIC ACID OXIDIZED L-Dehydro Ascorbic Acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number-
PubChem Substance ID440667
Beilstein Registry Number84277
EC Number207-720-6
Chemical Name Translation去氢抗坏血酸
Merck Number13,2886
LabNetwork Molecule IDLN00193565
InChIInChI=1S/C6H6O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2,5,7-8H,1H2/t2-,5+/m0/s1
Canonical SMILES-
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分类

  • Pharmaceuticals
  • {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis
  • Carbohydrates & Derivatives
  • Intermediates & Fine Chemicals
  • {SNA} Ascorbate, Cofactor, 代谢组学, 代谢通路, 代谢通路图中的代谢产物和辅酶分子, 细胞生物学

产品应用

  • The reversibly oxidized form of ascorbic acid.

相关文献及参考

  • Beil. 18 ,V,5,41
  • Bohndiek SE, Kettunen MI, et al., Hyperpolarized [1-13C]-ascorbic and dehydroascorbic acid: vitamin C as a probe for imaging redox status in vivo. J. Am. Chem. Soc. 133 , 11795-11801, (2011) 摘要
  • Frömberg A, Gutsch D, Schulze D, et al., Ascorbate exerts anti-proliferative effects through cell cycle inhibition and sensitizes tumor cells towards cytostatic drugs. Cancer Chemother. Pharmacol. 67 , 1157-1166, (2011) 摘要
  • Lee Y, Park CH, Ram Kim A, et al., The effect of ascorbic acid and dehydroascorbic acid on the root gravitropic response in Arabidopsis thaliana. Plant Physiol. Biochem. 49 , 909-916, (2011) 摘要
  • Monteiro, G., et al., Reduction of 1-Cys peroxiredoxins by ascorbate changes the thiol-specific antioxidant paradigm, revealing another function of vitamin C Proc. Natl. Acad. Sci. U. S. A. 104 , 4886-91, (2007) 摘要
  • Moubasher, et al.: J. Biol. Chem., 176, 633 (1948),
  • Regulus P, Desilets JF, Klarskov K, Wagner JR

安全信息

WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Signal word Warning
Hazard Codes Xn
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Storage condition -20 -20°C -20°C, Inert atmosphere, Light sensitive
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P301+P317
  • P330 Rinse mouth. 漱口
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • MOL 文件:490-83-5.mol
  • 图谱信息:去氢抗坏血酸(490-83-5)红外图谱(IR2) 去氢抗坏血酸(490-83-5)红外图谱(IR1)
  • Sigma Aldrich:490-83-5(sigmaaldrich)
  • F:1-8-10

系列性分类


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