Zinc(II) Dibutyldithiocarbamate 二丁基二硫代氨基甲酸锌

CAS 136-23-2 MFCD00067274

化学结构图

136-23-2
SMILES: CCCCN(CCCC)C(=S)S[Zn]SC(=S)N(CCCC)CCCC

化学属性

Mol. FormulaC18H36N2S4Zn
Mol. Weight474.13
Melting Point104-110 °C
Solubility不溶于水、甲醇、乙醇、汽油、稀碱,微溶于乙酸乙酯、丙酮,溶于苯。
Density1,21 g/cm3
Boiling Point257.7°C at 760 mmHg

别名和识别编码

Chemical NameZinc(II) Dibutyldithiocarbamate
MDL NumberMFCD00067274
CAS Number136-23-2
EC Number205-232-8
Synonym Zinc(II) dibutyldithiocarbamate {LY} Zinc(II) dibutyldithiocarbamate {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc(II) dibutyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN3917872
PubChem Substance ID87566937
Chemical Name Translation二丁基二硫代氨基甲酸锌
Wiswesser Line Notation4N4&YUS&S-ZN-SYUS&N4&4
Canonical SMILESCCCCN(CCCC)C(=S)[S-].CCCCN(CCCC)C(=S)[S-].[Zn+2]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Zinc Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Zinc

安全信息

RTECSZH0175000
Packing GroupIII
Signal word Warning
UN Number 3077
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P337+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P304+P340
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P305+P351+P338
  • P405 Store locked up. 上锁保管。
  • P333+P313
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P302+P350
Hazard Codes Xi,N
Safety Statements
  • S37 Wear suitable gloves 戴适当手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
Hazard Class9
GHS Symbol
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 290 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

WGK Germany3
Storage condition 2-8°C, stored under nitrogen, away from moisture {LY} 2-8°C, stored under nitrogen, away from moisture {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from mois

其他信息

  • 类别:农药
  • 毒性分级:高毒
  • 二丁基二硫代氨基甲酸锌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0227 二丁基二硫代氨基甲酸锌(II) Zinc(II) Dibutyldithiocarbamate 500G 1560元 2014/06/02 D0227 二丁基二硫代氨基甲酸锌(II) Zinc(II) Dibutyldithiocarbamate 25G 306元
  • MOL 文件:136-23-2.mol
  • 用途一:是有效的过氧化物分解剂,常与主抗氧剂并用,用于聚丙烯、聚氯乙烯,也用作橡胶胶粘剂和乳胶固化促进剂
  • 上游原料:二正丁胺
  • 外观性质:灰白色粉末,有特殊气味。
  • TCI Shanghai:二丁基二硫代氨基甲酸锌 Zinc(II) Dibutyldithiocarbamate,>;97.0%(T)(136-23-2)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 急性毒性:腹腔-小鼠 LD50: 100 毫克/公斤
  • 图谱信息:二丁基二硫代氨基甲酸锌(136-23-2)红外图谱(IR2) 二丁基二硫代氨基甲酸锌(136-23-2)红外图谱(IR1) 二丁基二硫代氨基甲酸锌(136-23-2)质谱(MS)
  • MSDS 信息:二丁基二硫代氨基甲酸锌(136-23-2).msds
  • 可燃性危险特性:可燃; 受热产生有毒氮氧化物,硫氧化物和氧化锌烟雾
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • TSCA:Yes

系列性分类


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