Amitraz 双甲脒

CAS 33089-61-1 MFCD00069396

化学结构图

33089-61-1
SMILES: CN(/C=N/C1=CC=C(C)C=C1C)/C=N/C1=CC=C(C)C=C1C

化学属性

Mol. FormulaC19H23N3
Mol. Weight293
Density0.98
Stability对光敏感
Melting Point84.0 to 88.0 deg-C

别名和识别编码

Chemical NameAmitraz
CAS Number33089-61-1
Synonym Amitraze 胺三氮螨,双虫脒,果螨杀,杀伐螨,N Edrizar ENT 27967 Ectodex N,N-Di-(2,4-xylyliminomethyl)methylamine Amitraz estrella Acarac BAAM Amitraz N-双(2,4-二甲苯亚氨基甲基)甲胺 N'-(2,4-Dimethylphenyl)-N-[[(2,4-dimethylphenyl)imino]methyl]-N-methyl-methanimidamide Azaform Apivar ND 双甲脒 Fumilat A Ovasyn Methanimidamide, 1,5-Di(2,4-dimethylphenyl)-3-methyl-1,3,5-triazapenta-1,4-diene N-Methyl-N'-2,4-xylyl-N-(N-2,4-xylylformimidoyl)formamidine Amigard N'-(2,4-Dimethylphenyl)-N-(((2,4-dimethylphenyl)imino)methyl)-N-methylmethanimidamide BTS 27,419 Azadieno N'-(2,4-Dimethylphenyl)-N-{[(2,4-dimethylphenyl)imino]methyl}-N-methylmethanimidamide NSC 324552 N,N-Bis(2,4-xylyliminomethyl)methylamine Boots bts 27419
MDL NumberMFCD00069396
PubChem Substance ID253662223
EC Number251-375-4
Chemical Name Translation双甲脒
Reaxys-RN2946590
Merck Number486
Beilstein Registry Number2946590
LabNetwork Molecule IDLN00007151
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分类

  • A, AM to AQ, Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Formamides, Insecticides, Pesticides, Pesticides & Metabolites
  • {SNA} A-B, Acaricides, Analytical Standards, Formamides, Insecticides, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Alphabetical Index of Analytical Standards, A, A-B, AM to AQ, Acaricides, All alphabetically sorted, Analytical Standards,

产品应用

  • 该品为广谱杀螨剂。主要用于果树、花卉、草莓和其他农业及园艺作物。防治螨类,特别对柑桔螨类有较好的效果。也用于防治棉铃虫、红铃虫;防治家畜寄生虫的蜱、螨、疥虫等。双甲脒是杀螨剂中药效较好的品种。
  • 校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。

相关文献及参考

  • Kern, S., et al.: Envir. Sci. Technol., 43, 7039 (2009),
  • Fu, W., et al.: Environ. Toxicol. Chem., 28, 1372 (2009),
  • Merck: 14,486
  • Amoli, J., et al.: Am. J. Food Technol., 4, 56 (2009),

安全信息

RTECSZF0480000
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+
  • P301+P312+P330
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P308+P311
  • P333+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes 9
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R48/22
  • R50/53
Storage condition 避光、阴凉、干燥处贮存。 <0°C 0-10°C
Hazard Class9
UN Number 3077
Packing GroupIII
{h

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 65 gm/m3/6H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 33,66,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 788 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C20,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JJTOEX Japanese Journal of Toxicology. (Yakugyo Jihosha, Hokushin Bldg.,
   2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo, 101, Japan)  V.1-   1988-
   Volume(issue)/page/year: 2,289,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 3571 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
   Behavioral - coma
   Cardiac - pulse rate
REFERENCE :
   HETOEA Human & Experimental Toxicology.  (Macmillan Press Ltd., Brunel Road,
   Houndmills, Basingstoke, Hampshire, RG21 2XS, UK) V.9- 1990-
   Volume(issue)/page/year: 16,600,1997

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 140 mg/kg
SEX/DURATION            : female 7 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - delayed effects
REFERENCE :
   NETEEC Neurotoxicology and Teratology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.9-    1987- Volume(issue)/page/year:
   16,65,1994

其他信息

  • 常温下每升溶剂中的溶解度为:水为1mg,丙酮或甲苯为300g以上。在酸性介质中不稳定。在潮湿条件下长期存放会缓慢分解。

系列性分类


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