(R)-Oxiran-2-ylmethanol (R)-缩水甘油

CAS 57044-25-4 MFCD00074873

化学结构图

57044-25-4
SMILES: OC[C@H]1CO1

化学属性

Mol. FormulaC3H6O2
Mol. Weight74.08
Refractive index1.4310 to 1.4350
Density1.116
Boiling Point56-57
Flash Point72°C

别名和识别编码

Chemical Name(R)-Oxiran-2-ylmethanol
Reaxys-RN79782
CAS Number57044-25-4
Beilstein Registry Number79782
PubChem Substance ID125307377
MDL NumberMFCD00074873
Synonym (+)-Glycidol (R)-(+)-1-Hydroxy-2,3-epoxypropane, (R)-(+)-Oxirane-2-methanol (R)-(+)-2,3-Epoxy-1-propanol (R)-(+)-glycidol (R)-(+)-环氧乙烷-2-甲醇 (R)-(+)-缩水甘油 (R)-2,3-Epoxypropan-1-ol (R)-2,3-epoxy-1-propanol (R)-2,3-epoxy-propan-1-ol (R)-Oxiranemethanol (R)-glycidol (R)-oxiranemethanol Oxiranemethanol, (R)- R(+)-glycidol R-(+)-Glycidol R-GLYCIDOL d-β,γ-oxido-propyl alcohol {} {} {uni_hamburg}
EC Number404-660-4
Chemical Name Translation(R)-缩水甘油
LabNetwork Molecule IDLN00193743
InChIKeyCTKINSOISVBQLD-UHFFFAOYSA-N
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; alcohol; ether; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks

产品应用

  • 用于在 furanocembrane（一种海洋天然产物）的合成中构建环氧乙烯基碘化物中间体的手性结构单元。

相关文献及参考

  • 1. Tetrahedron Lett. 47 , 6401, (2006)
  • Beil. 17 ,V,3,−1
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: ELINCS Title: Sixth publication of Elincs (according to Article 21 of Directive 67/548/EEC) Page: 1-131 Year: 2003 Keyword: European List of Notified Chemical Substances Internet Resource: http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CELEX:52003DC0642:EN:NOT Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=eli

安全信息

RTECSRR0508000
UN Number 2810
Signal word Danger
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition <0°C <;0 贮存温度:-20°C
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
GHS Symbol
WGK Germany3
Hazard Codes 6.1 T
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class6.1
Packing GroupIII 
TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 278,289,1992

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Sister chromatid exchange
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 200 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

Risk Statements
  • R2 Risk of explosion by shock, friction, fire or other sources of ignition 遇到震动、摩擦、火焰或者其它引燃物有爆炸危险
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R34 Causes burns 会导致灼伤
  • R45 May cause cancer 可能致癌
  • R60 May impair fertility 可能降低生殖能力
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks

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