(2R,3S)-(-)-N-Boc-6-Oxo-2,3-Diphenylmorpholine (2R,3S)-(-)-N-叔丁氧羰基-6-氧代-2,3-二苯基吗啉

CAS 112741-49-8 MFCD00074955

化学结构图

112741-49-8
SMILES: CC(C)(C)OC(=O)N1CC(=O)O[C@@H]([C@@H]1C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC21H23NO4
Mol. Weight353.41
Melting Point206 °C (dec.)(lit.)
TSCANo

别名和识别编码

Chemical Name(2R,3S)-(-)-N-Boc-6-Oxo-2,3-Diphenylmorpholine
Synonym (2R,3S)-(-)-6-氧代-2,3-二苯基-4-吗啉羧酸叔丁酯 tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenylmorpholine-4-carboxylate (2R,3S)-(-)-N-叔丁氧羰基-6-氧代-2,3-二苯基吗啉
MDL NumberMFCD00074955
PubChem Substance ID24860002
CAS Number112741-49-8
Chemical Name Translation(2R,3S)-(-)-N-叔丁氧羰基-6-氧代-2,3-二苯基吗啉
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Morpholines
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Morpholines

相关文献及参考

  • FT-IR 2 (2), 2919:D / FT-NMR 1 (2), 1323:C / RegBook 1 (2), 1951:A / Structure Index 1 , 314:B:4
  • Fieser 14 ,58 / Fieser 17 ,54

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Morpholines - Heterocyclic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Morpholines - Heterocyclic Building Blocks

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