1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophosphate 1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐

CAS 64536-78-3 MFCD00075097

化学结构图

64536-78-3
SMILES: [Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.C1CCCCC1P(C1CCCCC1)C1CCCCC1.C1=CC=CC=N1

化学属性

Melting Point175 °C (dec.)(lit.)
SolubilitySlightly soluble in acetone, dichloromethane, ethanol, diethyl ether
TSCANo
Mol. Formula[(C6H11)3P][C8H12][C5H5N]Ir+PF6ae
Mol. Weight805
Appearance orange xtl.
Stabilitymoisture sensitive

别名和识别编码

Chemical Name1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophosphate
Synonym Crabtree 催化剂 [Ir(cod)(PCy3)(py)]PF6 [Ir(cod)(PCy3)(py)]PF6 六氟磷酸(三环己基膦)(1,5-环辛二烯)(吡啶)合铱 铱(I)六氟磷酸(1,5-环辛二烯)-(吡啶)-(三环己基膦)复合物 Crabtree 催化剂 [Ir(cod)(PCy3)(py)]PF6 六氟磷酸(三环己基膦)(1,5-环辛二烯)(吡啶)合铱 铱(I)六氟磷酸(1,5-环辛二烯)-(吡啶)-(三环己基膦)复合物 Crabtree's catalyst 1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
PubChem Substance ID253659537
Chemical Name Translation1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
Reaxys-RN16178060
MDL NumberMFCD00075097
CAS Number64536-78-3
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium

相关文献及参考

  • Homogeneous catalyst, introduced by Crabtree, which can be used in non-coordinating solvents (e.g. DCM), and is one of the most active catalysts for homogeneous hydrogenation, effective even for tetrasubstituted alkenes: J. Organomet. Chem., 135, 395; 141, 205 (1977); Acc. Chem. Res., 12, 331 (1979). For a brief feature, see: Synlett, 160 (2001). Promotes stereoselective hydrogenations, directed by an adjacent OH: J. Am. Chem. Soc., 105, 1072 (1983), or carboxamide: J. Org. Chem., 50, 5905 (1985) group. For discussion of the influence of these and various other directing groups on the homogeneous hydrogenation of olefinic double bonds, see: J. Org. Chem., 51, 2655 (1986).
  • Has also been applied to the directed hydroboration of alkenes: J. Org. Chem., 55, 5678 (1990); J. Am. Chem. Soc., 113, 4042 (1991).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition Moisture Sensitive
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iridium 铱催化
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iridium 铱催化
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Indium
  1. Functional Group 官能团索引
  2. phosphine
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶
  1. Catalysts
  2. Iridium

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