(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate (双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)

CAS 65012-74-0 MFCD00078983

化学结构图

65012-74-0
SMILES: [Rh+].C[C@@H]([C@H](C)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1.[O-]Cl(=O)(=O)=O.C1C2C=CC1C=C2

化学属性

Mol. FormulaC35H32ClO4P2Rh
Mol. Weight716.93
Melting Point210 °C (dec.)(lit.)

别名和识别编码

Chemical Name(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate
MDL NumberMFCD00078983
PubChem Substance ID24860271
Synonym (双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)
Chemical Name Translation(双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)
CAS Number65012-74-0
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes O,Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S17 Keep away from combustible material 远离可燃物料;
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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