Poly(Vinyl Alcohol) 聚乙烯醇

CAS 9002-89-5 MFCD00081922

化学结构图

9002-89-5
SMILES: *C[C@H](*)O

化学属性

Mol. FormulaN/A
Mol. WeightN/A
TSCAYes
Melting Point>300 °C
Flash Point79°C
Density1.269
Refractive index1.49-1.53
Stability对湿度敏感
Solubility溶于热水
Boiling Point-14.5 °C at 760 mmHg

别名和识别编码

MDL NumberMFCD00081922
CAS Number9002-89-5
Synonym Polyvinyl alcohol {LY} Polyvinyl alcohol {} {LY} Polyvinyl alcohol {} {} {LY} Polyvinyl alcohol {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Polyvinyl alcohol {} {} {} {} {} {} {} {} {} {} {
EC Number209-183-3
Chemical NamePoly(Vinyl Alcohol)
Chemical Name Translation聚乙烯醇
PubChem Substance ID11199
Merck Number7585
InChIInChI=1S/C2H4O/c1-2-3/h2-3H,1H2
Canonical SMILESC=CO.[n]
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Indicators,
  • {SNA} 3D Printing Materials for Research and Development,
  • {SNA} Hydrophilic Polymers,
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Organic Soluble Polymers, P, POLB - POLY, Poly(vinyl alcohol), Polymer Standards
  • {SA} Alphabet

产品应用

  • 接合剂及成层剂,织物,纸张上浆剂,增厚剂和稳定剂,乳化剂。

相关文献及参考

  • Merck: 14,7585

安全信息

RTECSTR8100000
WGK Germany1
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P308+P311
GHS Symbol
Hazard statements
  • H371 May cause damage to organs 可能导致器官损伤
Signal word Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes Xn
Risk Statements
  • R68/20/21/22
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Implant
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Immunological Including Allergic - increase in cellular immune response
REFERENCE :
   BJSUAM British Journal of Surgery.  (Quadrant Subscription Services Ltd.,
   Oakfield House, Perrymount Rd., Haywards Heath, W. Sussex RH16 3DH, UK) V.1-
      1913-  Volume(issue)/page/year: 52,49,1965

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Skin and Appendages - tumors
REFERENCE :
   AMPLAO AMA Archives of Pathology.  (Chicago, IL)  V.50(4)-69, 1950-60.  For
   publisher information, see APLMAS.  Volume(issue)/page/year: 67,589,1959

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Implant
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3768 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 19,424,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 23854 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Gastrointestinal - hypermotility, diarrhea
   Liver - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(5),9,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14700 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle weakness
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(10),75,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14270 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Gastrointestinal - hypermotility, diarrhea
   Liver - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(5),9,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >20 gm/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle weakness
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For Engli

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 14700 mg/kg
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 53(9),83,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 14700 mg/kg
SEX/DURATION            : female 35 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 53(9),83,1988

其他信息

  • 外观性质:乳白色粉末。
  • RTECS号:TR8100000
  • NIST化学物质信息:Polyvinyl alcohol(9002-89-5)
  • 用途:主要作维纶原料,亦可制薄膜、皮革粘合剂、纸加工剂、织物整理剂、107乳胶等
  • EPA化学物质信息:Ethenol, homopolymer(9002-89-5)
  • 生产方法:由醋酸乙烯酯经皂化而成
  • 稳定性:Stable. Combustible. Dust may form explosive mixtures with air. Incompatible with strong oxidizing agents.
  • 海关编码:39053000
  • 在200℃时软化而分解。商品因存在各种乙酰基残留物,故不同的粘度和特性。能溶于水,不溶于石油溶剂。
  • MOL 文件:9002-89-5.mol
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 聚乙烯醇 糖果、巧克力制品包衣 被膜剂 18.0
  • 聚乙烯醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30153270 聚乙烯醇 kg 30.8元 2011/08/23 30153160 聚乙烯醇1750±50 500g 21元 2011/08/23 30153083 聚乙烯醇 AH-26 250g 16元
  • 毒害物质数据:9002-89-5(Hazardous Substances Data)

系列性分类


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