Triirondodecacarbonyl 十二羰基三铁

CAS 17685-52-8 MFCD00135617

化学结构图

17685-52-8
SMILES: O#C[Fe]1(C#O)(C#O)(C#O)[Fe](C#O)(C#O)(C#O)(C#O)[Fe]1(C#O)(C#O)(C#O)C#O

化学属性

Mol. FormulaFe3(CO)12
Mol. Weight503.66
Melting Point165 °C (dec.)(lit.)
Density2.00
TSCANo
Appearance black xtl.
Stabilityair sensitive, store cold

别名和识别编码

Chemical NameTriirondodecacarbonyl
Synonym Iron, di-μ-carbonyldecacarbonyltri-, triangulo Di-μ-carbonyldecacarbonyltri-triangulo-iron Iron carbonyl (Fe3(CO)12) di μ carbonyldecacarbonyl triangulo triiron Fe3 (CO)12 Iron, di μ carbonyldecacarbonyltri-, triangulo Dodecacarbonyltriiron Eisencarbonyl C12Fe3O12 Tri-irondodecacarbonyl tri-Eisendodecacarbonyl 十二羰基三铁 di-μ-carbonyldecacarbonyl-triangulo-triiron Dodecacarbonyl-triangulo-triiron Dodecacarbonyltriiron 三铁十二羰基 Triiron dodecacarbonyl Dodecacarbonyltriiron(0) Di-μ-carbonyldecacarbonyltriiron Iron, di-μ-carbonyldecacarbonyltri-, triangulo- Trieisendodecacarbonyl
MDL NumberMFCD00135617
EC Number241-668-5
CAS Number17685-52-8
PubChem Substance ID24863814
Chemical Name Translation十二羰基三铁
InChIKeyBEABFUPOCAPMLB-UHFFFAOYSA-N
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分类

  • {uni_hamburg} no charge; metal-organic; other heterocycle; fused rings; 3ring; 4ring; metal carbonyl; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Non-Precious Metal Catalysis
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron

相关文献及参考

  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nu

安全信息

Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S1 Keep locked up 上锁；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Packing GroupII
UN Number UN3179
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R68/20/21/22
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
Storage condition Air & Moisture Sensitive
WGK Germany3
GHS Symbol
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P307+P311
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H370 Causes damage to organs 导致器官损伤
Hazard Codes F,T

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Iridium
  1. Metal Carbonyls
  2. Iron

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