(+)-1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene (+)-1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯

CAS 136779-28-7 MFCD00142321

化学结构图

136779-28-7
SMILES: CC[C@H]1CC[C@H](CC)P1C1=CC=CC=C1P1[C@H](CC[C@@H]1CC)CC

化学属性

Mol. FormulaC22H36P2
Mol. Weight362.47
Density1.010 g/mL at 25 °C
Refractive indexn20/D 1.581
Appearance colorless oil
Stabilityair sensitive

别名和识别编码

Chemical Name(+)-1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene
Synonym (2S,2′S,5S,5′S)-2,2′,5,5′-四乙基-1,1′-(邻亚苯基)二磷烷 (S,S)-乙基-DUPHOS (+)-1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯
MDL NumberMFCD00142321
PubChem Substance ID24884986
Beilstein Registry Number4814174
CAS Number136779-28-7
Chemical Name Translation(+)-1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

安全信息

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. BPE
  2. Phosphorus
  1. DUPHOS
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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