(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉

CAS 105251-52-3 MFCD00142698

化学结构图

105251-52-3
SMILES: C[Si](C)(OC[C@@H]1CC/C(/N1)=C(\C#N)/C1CC[C@@H](CO[Si](C)(C)C(C)(C)C)N=1)C(C)(C)C

化学属性

Mol. FormulaC24H45N3O2Si2
Mol. Weight463.80
Melting Point74-77 °C

别名和识别编码

Chemical Name(1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin >=97.0%
Synonym 半咕啉手性配体 2 (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉
MDL NumberMFCD00142698
PubChem Substance ID57647178
Beilstein Registry Number5153664
CAS Number105251-52-3
Chemical Name Translation(1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. H. Fritschi et al. Helv. Chim. Acta 71 , 1553, (1988)
  • 2. U. Leutenegger et al. Angew. Chem. 101 , 61, (1989)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes

相关产品推荐