(S,S)-DUTHALER-HAFNER REAGENT

CAS 140462-73-3 MFCD00143373

化学结构图

140462-73-3
SMILES: CC1(C)O[C@@H](OC(C2C=CC=CC=2)C2C=CC=CC=2)[C@@H](O1)OC(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ti].[CH]1[CH][CH][CH][CH]1 |^1:37,38,39,40,41|

化学属性

Mol. FormulaC31H30O4.C5H5.ClTi
Mol. Weight612.96
Melting Point209-213 °C

别名和识别编码

Chemical Name(S,S)-DUTHALER-HAFNER REAGENT
Synonym (4S,5S)-氯-环戊二烯基-[2,2-二甲基,-1,3-二氧戊环-4,5-双(二苯基甲氧基)]钛 (S,S)-Duthaler-Hafner reagent [(4S,5S)-2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]环戊二烯基-氯化钛 (S,S)-Duthaler-Hafner reagent [(4S,5S)-2,2-Dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]cyclopentadienyl-chlorotitanium
PubChem Substance ID24868490
CAS Number140462-73-3
MDL NumberMFCD00143373
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Allylation, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs

相关文献及参考

  • 1. Hafner, A. et al. J. Am. Chem. Soc. 114 , 2321, (1992)
  • 2. Duthaler, R.O. Hafner, A. Chem. Rev. 92 , 807, (1992)
  • 3. Duthaler, R.O. et al. Pure Appl. Chem. 64 , 1897, (1990)
  • 4. Duthaler, R.O. et al. Inorg. Chim. Acta 222 , 95, (1994)
  • 5. Duthaler, R.O. et al. Pure Appl. Chem. 62 , 631, (1990)
  • Merck 14 ,3472
  • FT-IR 2 (3), 4571:C

安全信息

Hazard Codes C
WGK Germany3
GHS Symbol
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Allylation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. TADDOLs - Privileged Ligands and Complexes

相关产品推荐