Ferric Nitrate Nonahydrate 硝酸铁(III)九水合物
CAS 7782-61-8 MFCD00149708
化学结构图
SMILES: O.O.O.O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Fe+3]
化学属性
| Mol. Formula | FeN3O9·9H2O |
|---|---|
| Mol. Weight | 404 |
| Density | 1.684 |
| Melting Point | 47 |
| TSCA | Yes |
| Boiling Point | 125° dec. |
| Solubility | Freely soluble in water, alcohol, acetone. Slightly soluble in cold and concentrated HNO3 |
| Stability | 对空气敏感 ,易吸潮 |
| Flash Point | 125°C |
| Appearance | 无色至浅紫色单斜结晶。熔点47.2℃。相对密度1.684。加热至125℃时分解。易溶于水，溶于乙醇和丙酮，微溶于硝酸。易潮解。有氧化性。 |
别名和识别编码
| Chemical Name | Ferric Nitrate Nonahydrate |
|---|---|
| CAS Number | 7782-61-8 |
| EC Number | 233-899-5 |
| Beilstein Registry Number | 2384789 |
| MDL Number | MFCD00149708 |
| Synonym | FERRIC NITRATE 9H2O FERRIC NITRATE NONAHYDRATE FERRIC NITRATE NONAHYDRATE, ACS, 98-101 % Ferric nitrate nonahydrate IRON (III) NITRATE, HYDROUS IRON(III) NITRATE ENNEAHYDRATE IRON(III) NITRATE NONAHYDRATE IRON(III) NITRATE NONAHYDRATE, 98+%, A.C .S. REAGENT Iron(III) nitrate nonahydrate Iron(III) nitrate nonahydrate, 99.999+% metals basis Ironnitratenonahydratecolorlesspalevioletxtl nitricacid,iron(3+)salt,nonahydrate 九水合硝酸铁 九水硝酸铁 硝酸铁 硝酸铁(III) 九水合物 硝酸铁(III) 九水合物, ACS, 98.0-101.0% 硝酸铁(III) 水合物, PURATRONIC|R, 99.999% (METALS BASIS) 硝酸铁,九水 |
| PubChem Substance ID | 24894966 |
| Merck Number | 14,4027 |
| Chemical Name Translation | 硝酸铁(III)九水合物 |
| LabNetwork Molecule ID | LN00194165 |
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分类
- {SNA} Miscellaneous Reagents and Supplements, 细胞培养, 试剂和添加剂
- {Chemicalbook} 无机化工产品: 无机盐: Cl硝酸盐
- {SA} Fe, Iron Salts, Materials Science, Metal and Ceramic Science, Salts, Ultra-High Purity Materials
- {SNA} Cell Culture, Miscellaneous Reagents and Supplements, Reagents and Supplements
- {SNA}
- {SNA} Alternative Energy, Dopants, Fe, Iron Salts, Materials Scien
- {SNA} Alternative Energy, Dopants, Essential Chemicals, Fe, Iron Salts, Materials Science, Metal and Ceramic Science, Phosphor Materials, Research Essentials, Salts, Ultra-High Purity Materials
产品应用
- 分析试剂(吸收乙炔)、催化剂，铜着色剂
相关文献及参考
- Catalyst for preparation of alkali metal amides from the metals in liquid ammonia (numerous Organic Syntheses references).
- For use in regioselective mononitration of phenols, see: Tetrahedron, 45, 1415 (1989). The reaction can also be carried out in an ionic liquid: Synth. Commun., 33, 961 (2003).
- Merck: 14,4027
- Details have been given for an improved method for preparation of the useful oxidizing agent potassium ferrate(VI) by oxidation with hypochlorite, and subsequent use, supported on Montmorillonite K10 clay, for the selective oxidation of benzyl alcohol or benzylamine to benzaldehyde, thiols to disulfides, aniline to azobenzene and various oximes and hydrazones to the parent ketone: J. Org. Chem., 61, 6360 (1996).
- On a clay support, cleaves 2,4-dinitrophenylhydrazones: Synthesis, 439 (1985).
安全信息
GHS Symbol
- S17 Keep away from combustible material 远离可燃物料；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
- H319 Causes serious eye irritation 严重刺激眼睛
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
其他信息
- 上游原料:氮 --> 铁屑 --> 硝酸铁
- 微有潮解性，加热至129°C时分解。溶于水、乙醇和丙酮，微溶于冷浓硝酸。
- Alfa Aesar:硝酸铁(III)水合物,Puratronic|r,99.999%(metalsbasis) Iron(III) nitrate hydrate, Puratronic, 99.999% (metals basis)(7782-61-8)
- 图谱信息:硝酸铁(九水)(7782-61-8)红外图谱(IR2) 硝酸铁(九水)(7782-61-8)红外图谱(IR1)
- 微有潮解性，加热至127°C时分解。溶于水、乙醇和丙酮，微溶于冷浓硝酸。
- 参考质量标准:参考标准 指标名称 指标(工业级) 硝酸铁[Fe(NO3)3·9H2O]含量/% 98.0～101 不溶物/%≤ 0.005 氯化物(以Cl - 计)/%≤ 0.0005 硫酸盐(以SO4 2- 计)/%≤ 0.1 氢氧化氨不沉淀物/%≤ 0.1
- Acros Organics:九水硝酸铁(III) Iron(III) nitrate nonahydrate, for analysis ACS, 98+%(7782-61-8)
- MOL 文件:7782-61-8.mol
- 海关编码:28342980
- MSDS 信息:Ferric nitrate nonahydrate(7782-61-8).msds
- 用途一:用作催化剂，媒染剂，金属表面处理剂，氧化剂，分析试剂，放射性物质吸附剂。
- 微有潮解性，加热至128°C时分解。溶于水、乙醇和丙酮，微溶于冷浓硝酸。
- 微有潮解性，加热至125°C时分解。溶于水、乙醇和丙酮，微溶于冷浓硝酸。
- F:3-9-23
- 硝酸铁(九水)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80072718 硝酸铁 500g 16.8元 2010/06/21 202490010 硝酸铁(九水) Iron(III) nitrate nonahydrate 99+%, for analysis 1 KG 1534元 2010/06/21 202492500 硝酸铁(九水) Iron(III) nitrate nonahydrate 99+%, for analysis 250 GR 540元
- Sigma Aldrich:7782-61-8(sigmaaldrich)
- 用途二:分析试剂(吸收乙炔)、催化剂，铜着色剂
- 方法一:铁屑法将相对密度1.38的硝酸加入已盛有水的耐酸反应器中，加热至40～50℃，缓慢加入细铁屑进行反应，反应3h，将溶液加热，逐出氧化氮气体。过滤，把滤液蒸发浓缩至形成结晶膜，送人冷却结晶器冷却至0℃以下析出结晶，经吸滤，结晶用20％硝酸洗涤。制得硝酸铁成品。其反应式如下。 Fe+4HNO3→Fe(NO3)3+NO+2H2O Fe+6HNO3→Fe(NO3)3+3NO2+3H2O 母液可循环使用。反应过程中放出的氧化氮气体，工业上常用烧碱溶液吸收，因其吸收速度较快，得到的中和液，用于生产硝酸钠。
- 毒性:对皮肤有刺激作用，表现为皮肤剧烈瘙痒，毛囊周围发红。吸入其粉尘会引起慢性胃炎、胆囊炎。 生产人员操作时要穿工作服，戴防护口罩，乳胶手套等劳保用品。防止吸入粉尘，保护呼吸器官和皮肤，生产设备要密闭，车间通风应良好，下班后要洗澡，保护皮肤。
- 微有潮解性，加热至126°C时分解。溶于水、乙醇和丙酮，微溶于冷浓硝酸。
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