Ruthenium(III)Chloride Hydrate 三氯化钌(III)水合物
CAS 14898-67-0 MFCD00149844
化学结构图
SMILES: [Cl-].[Cl-].[Cl-].[Ru+3]
化学属性
| Mol. Formula | RuCl3· xH2O |
|---|---|
| Mol. Weight | 207.43 (anhydrous basis) |
| Melting Point | >300 |
| Solubility | Very soluble in water. Soluble in alcohol, acetone |
| TSCA | Yes |
| Density | 1.422 |
| Stability | 易吸潮 |
| Appearance | black pwdr. |
别名和识别编码
| Chemical Name | Ruthenium(III)Chloride Hydrate |
|---|---|
| CAS Number | 14898-67-0 |
| PubChem Substance ID | 24852386 |
| EC Number | 233-167-5 |
| MDL Number | MFCD00149844 |
| Merck Number | 14,8302 |
| Synonym | Ruthenium(III) chloride hydrate, ReagentPlus®, 活性矾土 RUTHENIUM CHLORIDE HYDRATE ruthenium(iii) chloride hydrate, premion 氯化钌(III)水合物, PREMION|R, 99.99% (METALS BASIS) RUTHENIUM(III) CHLORIDE HYDRATE (35-40% RU) RUTHENIUM(III) CHLORIDE HYDRATE RutheniumchloridehydrateRu RUTHENIUM TRICHLORIDE N-HYDRATE 三氯化钌 三氯化钌水合物 氯化钌(III)水合物, 99.9% (PGM BASIS), RU 38% MIN Active oxidative aluminum Ruthenium trichloride 三氯化钌 水合物 RUTHENIUM(III)CHLORIDEHYDRATE,35-42%RU activated alumin(I)um oxide 三水氯化钌 RUTHENIUM(III) CHLORIDE RUTHENIUM TRICHLORIDE HYDRATE Ruthenium(III) chloride hydrate, 99.98% metals basis RUTHENIUM(+3)CHLORIDE HYDRATE 三氯化钌(III)水合物,;氯化钌(III)水合物 氯化釕 Ruthenium(III)-chlorid-hydrat RUTHENIUM(III) CHLORIDE N-HYDRATE RUTHENIUM CHLORIDE, HYDRATED REAGENT Ruthenium trichloride Trichlororuthenium hydrate 氯化钌(III)水合物 RUTHENIUM CHLORIDE, HYDROUS Ruthenium chloride (RuCl3), hydrate RUTHENIUM (III) CHLORIDE HYDRATE (40-43% RU) (99.9%-RU) 活性氧化铝 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 三氯化钌(III)水合物 |
| LabNetwork Molecule ID | LN00198876 |
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分类
- {S
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Ca
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hematology Stains, Hematology and Histology,
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Catalysts, Ruthenium, Ruthenium Salts, Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Catalysts,
产品应用
- 1.多相催化或均相催化
- 2.电镀、电解阳极
- 与氧化剂发生氧化反应的催化剂
相关文献及参考
- In the presence of NaOH, is a catalyst for the high-yield rearrangement of sec-allylic alcohols to saturated ketones: J. Chem. Soc., Chem. Commun., 594 (1980). In MeOH, allyl alcohols are converted to allyl ethers. The thermodynamically more stable isomer predominates: Synth. Commun., 12, 807 (1982):
- Merck 14 ,8302
- Used catalytically, in the presence of a suitable reoxidant, such as periodate or sometimes hypochlorite, RuCl3 is a source of the powerful oxidizing agent, ruthenium(VIII) oxide, RuO4: J. Org. Chem., 46, 3936 (1981); J. Am. Chem. Soc., 103, 464 (1981).
- Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, employing only 0.5 mol% catalyst, see: Org. Lett., 5, 3353 (2003). For oxidation of diols to carboxylic acids: J. Org. Chem., 53, 5185 (1988). `,a-Enones to carboxylic acids: J. Org. Chem., 52, 689 (1987). Alkynes to `-diketones: Helv. Chim. Acta, 71, 237 (1988). Ethers to esters: Tetrahedron Lett., 24, 3829 (1983). Amines to amides: Chem. Pharm. Bull., 36, 3125 (1988). Methylbenzenes to benzoic acids: J. Org. Chem., 51, 2880 (1986). For the oxidation of alkenes, al
- For a brief survey of uses of RuC3 in Organic synthesis, see: Synlett, 1974 (2007).
- In the presence of 2,2'-bipyridine, catalyzes the stereospecific epoxidation of alkenes. The configuration of the alkene is retained: Tetrahedron Lett., 25, 3187 (1984).
- Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, emplo
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
其他信息
- 外观性质:为带有光泽的晶体颗粒，一般呈灰褐色或暗红色，有腐蚀性，极易潮解，溶于水、醇、丙酮和乙酸乙酯中中，在热水中分解。
- Sigma Aldrich:14898-67-0(sigmaaldrich)
- Alfa Aesar:氯化钌(III)水合物,Premion|r,99.99%(metalsbasis) Ruthenium(III) chloride hydrate, Premion, 99.99% (metals basis)(14898-67-0)
- 用途二:1.多相催化或均相催化2.电镀、电解阳极3.电子工业等重要化工原料
- 用途一:用作干燥剂、吸附剂、催化剂载体
- 下游产品:2-(3-溴-6-甲基-2-吡嗪酮-1(2H)-基)乙酸乙酯 --> 2-(3,4-二氢-6-甲基-2,3-二氧代吡嗪-1(2H)-基)乙酸乙酯 --> 三苯基膦氯化钌 --> 环辛二烯二氯化钌(II) --> 三联吡啶氯化钌六水合物
- Acros Organics:三氯化钌水合物 Ruthenium(III) chloride hydrate, 35 - 40% Ru(14898-67-0)
- 三氯化钌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 51022021 水合三氯化钌 1g 150元 2010/06/21 195480250 三氯化钌 Ruthenium(III) chloride hydrate , 35 - 40% Ru 25 GR 3628元 2010/06/21 195480010 三氯化钌 Ruthenium(III) chloride hydrate , 35 - 40% Ru 1 GR 311元
- 敏感性:Hygroscopic
- 一般呈灰褐色或暗红色，有腐蚀性，极易潮解，溶于水、醇、丙酮和乙酸乙酯中中，在热水中分解。
- MOL 文件:14898-67-0.mol
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