Tetrabutylammonium fluoride hydrate 四丁基氟化铵三水合物

CAS 87749-50-6 MFCD00149981

化学结构图

87749-50-6
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.O.O.O.[F-]

化学属性

Mol. FormulaC16H42FNO3
Mol. Weight316
Melting Point62-63
TSCAT
Density0.887
Flash Point-17 ºC
Stability易吸潮

别名和识别编码

Chemical NameTetrabutylammonium fluoride hydrate
CAS Number87749-50-6
Alfabeta NameTETRABUTYLAMMONIUMFLUORIDETRIHYDRATE N--
MDL NumberMFCD00149981
EC Number207-057-2
Beilstein Registry Number3570522
Synonym TBAF Hydrate Tetrabutylammoniumfluoridetrihydrate97% 三水 四丁基氟化铵 三水合物
PubChem Substance ID57653206
Chemical Name Translation四丁基氟化铵三水合物
LabNetwork Molecule IDLN00119197
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分类

  • {SNA} Chemical Synthesis, Deprotecting Reagents, Fluoride Sources, Protection and Derivatization, Synthetic Reagents

产品应用

  • 裂解甲硅烷基醚和其它硅烷基保护集团的试剂; 催化各种硅复合物反应的催化剂。

相关文献及参考

  • Beilstein: 4,III,292

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
UN Number 1759 UN2811
Storage condition 易吸潮，密封保存。 Hygroscopic
Hazard Codes 8 C
Hazard Class6.1

其他信息

  • Sigma Aldrich:87749-50-6(sigmaaldrich)
  • 溶解于水，无水TBAF不稳定。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Deprotecting Reagents - Protection and Derivatization
  5. Fluoride Sources - Deprotecting Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Deprotecting Reagents
  1. Functional Group 官能团索引
  2. quaternary ammonium salt
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂