Ammonium iron(III) sulfate dodecahydrate 硫酸铁(III)铵十二水合物

CAS 7783-83-7 MFCD00150004

化学结构图

7783-83-7
SMILES: N.O.O.O.O.O.O.O.O.O.O.O.O.O=S(=O)([O-])O.O=S(=O)([O-])[O-].[Fe+3]

化学属性

Mol. FormulaNH4Fe(SO4)2· 12H2O
Mol. Weight482.19
Melting Point39-41
Density1.710
TSCAYes
SolubilitySoluble in water (1240 mg/ml at 25 °C), and 1% (v/v) aqueous HCl (100 mg/ml). Insoluble in alcohol.
Boiling Point230 °C at 760 mmHg
Refractive index1.4854
Stability对光线敏感,易吸潮
Appearance pale purple xtl.

别名和识别编码

Chemical NameAmmonium iron(III) sulfate dodecahydrate
Synonym Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate, 99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium iron(Ⅲ) sulfate dodecahydrate
CAS Number7783-83-7
PubChem Substance ID197097
EC Number233-382-4
MDL NumberMFCD00150004
Merck Number14,521
Beilstein Registry Number2384789
Chemical Name Translation硫酸铁(III)铵十二水合物
LabNetwork Molecule IDLN00192981
InChIInChI=1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3
Canonical SMILESOS(=O)([O-])=O.O=S([O-])([O-])=O.[12].N.O.[Fe+3]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron Catalysts
  • {SA} A-B, Puriss p.a., Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Puriss p.a.
  • {SNA} ACS Grade, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents,

产品应用

  • An oxidation resistant analytical standard.

相关文献及参考

  • Merck: 14,518

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSWS5900000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P305+P351+P338
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen Store at RT. {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect

其他信息

  • Ammonium iron(III) sulfate dodecahydrate is often employed as an analytical standard, and has been used in a variety of other applications from nanomaterials to general redox reactions. This product is much less affected by oxygen in the air than iron(II) sulfate, making it more desirable for titration purposes, where iron(II) might be oxidized to iron(III). The oxidation of iron(II) to iron(III) is pH dependent, and the reaction occurs more rapidly at higher pH; this product lowers the pH of solutions slightly, thereby preventing oxidation from occurring.
  • 无气味,有收敛酸味。有风化性。易溶于水,几乎不溶于醇。0.1mol/L水溶液pH为2.5。230℃失去12分子结晶水。有刺激性
  • 无气味,有收敛酸味。有风化性。易溶于水,几乎不溶于醇。0.1mol/L水溶液pH为2.5。230℃失去12分子结晶水。有刺激性。
  • MSDS 信息:Ferric ammonium sulfate dodecahydrate(7783-83-7).msds
  • Alfa Aesar:十二水合硫酸铁铵(III),ACS,98.5-102.0% Ammonium iron(III) sulfate dodecahydrate, ACS, 98.5-102.0%(7783-83-7)
  • F:3
  • Sigma Aldrich:7783-83-7(sigmaaldrich)
  • 图谱信息:十二水合硫酸铁铵(7783-83-7)红外图谱(IR1) 十二水合硫酸铁铵(7783-83-7)红外图谱(IR2)
  • 十二水合硫酸铁铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10001818 硫酸高铁铵;十二水合硫酸铁铵;硫酸铁铵;铁铵矾;硫酸铁(Ⅲ)铵;铁明矾 500g 14元 2011/08/23 10001828 硫酸高铁铵;十二水合硫酸铁铵;硫酸铁铵;铁铵矾;硫酸铁(Ⅲ)铵;铁明矾 500g 13元 2010/06/21 423690250 十二水合硫酸铁铵 Ammonium iron(III) sulfate dodecahydrate 99%, for analysis ACS 25 GR 451元
  • Acros Organics:十二水硫酸铁铵 Ammonium iron(III) sulfate dodecahydrate, for analysis, 99+%(7783-83-7)
  • 外观性质:无色至淡紫色透明八面形结晶,无气味,有收敛酸味。有风化性。易溶于水,几乎不溶于醇。0.1mol/L水溶液pH为2.5。230℃失去12分子结晶水。有刺激性。密度:1.71熔点: 37℃折光率:1.4854
  • MOL 文件:7783-83-7.mol
  • 海关编码:28333000
  • 用途一:测定卤素的指示剂,银量法指示剂,媒染剂,氮肥生产中测定纯碱含铁量,分析金属盐溶液的氰化物,配高铁的标准。

系列性分类


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