Copper(Ii)Tetrafluoroborate Hydrate 四氟硼酸铜(II)水合物
CAS 207121-39-9 MFCD00150223
化学结构图
SMILES: F[B-](F)(F)F.F[B-](F)(F)F.O.[Cu+2]
化学属性
| Mol. Formula | Cu(BF4)2· xH2O |
|---|---|
| Mol. Weight | 237.16 (anhydrous basis) |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Copper(Ii)Tetrafluoroborate Hydrate |
|---|---|
| MDL Number | MFCD00150223 |
| EC Number | 253-959-4 |
| CAS Number | 72259-10-0 |
| PubChem Substance ID | 24862673 |
| Synonym | Copper(II)tetrafluoroborate hydrate 四氟硼酸铜 水合物 |
| Chemical Name Translation | 四氟硼酸铜(II)水合物 |
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分类
- {SNA} Copper Salts, Materials Science, Metal and Ceramic Science, Salts
- {SNA} Copper Salts, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
相关文献及参考
- Catalyst for acetylation of alcohols, phenols, thiols or amines with acetic anhydride, effective at 1 mol % under solvent-free conditions: Synthesis, 111 (2004). The method has also been applied to the formation of 1,1-diacetates from aldehydes: Synthesis, 831 (2004). Under similar conditions, conjugate addtion of thiols to ɑ,ß-unsaturated carbonyl compounds can be effected: Tetrahedron Lett., 46, 1721 (2005). Catalyzes the ring-opening of epoxides by alcohols: Org. Lett., 4, 2817 (2002), or amines: Tetrahedron Lett., 46, 2675 (2005). Aldehydes and ketones are converted to their dimethyl or diethyl acetals in high yield with the corresponding orthoformates: Tetrahedron Lett., 46, 8319 (2005). Efficient conversion to 1,3-dithiolanes or 1,3-dithianes can also be achieved: Tetrahedron Lett., 46, 6213 (2005). Rapid and efficient formation of Boc derivatives of amines with Di-tert-butyl dicarbonate, A14708 has also been described: Tetrahdron Lett., 47, 1087 (2006).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
GHS Symbol
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
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