Phenylmercury Nitrate 硝酸苯汞

CAS 8003-05-2 MFCD00151098

化学结构图

8003-05-2
SMILES: O=[N+]([O-])O[Hg]c1ccccc1.O[Hg]c1ccccc1

化学属性

Mol. FormulaC{1}{2}H{1}{1}Hg{2}NO{4}
Mol. Weight634.42
Melting Point188°C
TSCANo
Appearance #EndEditable "Content" 白色珠光鳞片结晶。熔点188℃（分解）。微溶于醇，极微溶于水，几乎不溶于醚，可缓慢溶于甘油。 制备方法：由乙酸苯汞与硝酸钠反应制得。 用途：在医药工业用作防腐剂和避孕药的原料。
Stability对光敏感

别名和识别编码

Chemical NamePhenylmercury Nitrate
Synonym hydroxy(nitrato)diphenyldi-mercur hydroxy(nitrato)diphenyldi-Mercury 硝酸苯汞 硝酸基苯汞与羟基苯基汞的化合物 Mercury,hydroxy(nitrato)diphenyldi- Mercurynitratophenyl-,cmpd.withhydroxyphenylmercury(1:1) 苯硝酸汞 PHENYLMERCURIC NITRATE, BASIC 碱性硝酸苯汞 苯基硝酸汞 Mercury,hydroxyphenyl-,cmpd.withnitratophenylmercury(1:1) Merphenyl nitrate, basic PHENYLMERCURIC NITRATE 硝酸苯汞(碱式) 苯基硝酸汞(II) DZ 硝酸基苯汞与羟基苯基汞(1:1)的化合物 PHENYLMERCURY NITRATE BASIC 硝基苯酚汞 hydroxyphenyl-mercurcmpd.withnitratophenylmercury(1:1) Mercury, hydroxyphenyl-, cmpd. with nitratophenylmercury (1:1) 硝酸苯汞碱 nitratephenylmercurique 苯基硝酸汞(II), BASIC Phenylmercuric nitrate, basic Merphene Nitrate phenyl mercurique Phenmerzyl nitrate, basic Mercuriphenyl nitrate cmpd.withhydroxyphenylmercury(1:1) Gyne-merfen (Nitrato-O)phenylmercury, basic PHENYLMERCURY NITRATE 硝酸苯基汞 dz Mercury, hydroxy(nitrato)diphenyldi- Merfen-styli
MDL NumberMFCD00151098
PubChem Substance ID24887410
CAS Number8003-05-2
Merck Number14,7302
EC Number200-242-9
Chemical Name Translation硝酸苯汞
Wiswesser Line NotationWNO-HG-R &622
LabNetwork Molecule IDLN02124764
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分类

  • {SNA} Chemical Synthesis, Organomercury, Organometallic Reagents

产品应用

  • 用作医药工业，如作防腐剂和避孕剂的原料之一，也可以用作除草剂、杀菌剂、熏剂等。

相关文献及参考

  • Merck: 14,7302 Beilstein: 16,IV,1720
  • Merck: 14,7302

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H301 Toxic if swallowed 吞食有毒
RTECSOW8575000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupII
UN Number UN 1895 6.1/PG 2 UN1895
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R25 Toxic if swallowed 吞咽有毒
  • R48/24/25
  • R50/53
Hazard Codes T,N
Hazard Class6.1
Storage condition 密封避光保存 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/year:
   12,212,1939

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 27 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/year:
   12,212,1939

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 45 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/year:
   12,212,1939

其他信息

  • 职业标准:TWA 0.05 毫克 (汞)/ 立方米; STEL 0.15 毫克 (汞)/ 立方米
  • 可燃性危险特性:可燃, 火场排出含汞, 氮氧化物辛辣刺激烟雾
  • 方法一:由乙酸苯汞与硝酸钠反应制得。 用途：在医药工业用作防腐剂和避孕药的原料。 #EndEditable "Content"
  • 类别:有毒物质
  • 储运特性:库房低温, 通风, 干燥; 与食品原料分开存放; 与还原剂, 有机物分开存放
  • 图谱信息:硝酸苯汞(8003-05-2)红外图谱(IR1)
  • Alfa Aesar:苯基硝酸汞(II),basic Phenylmercury(II) nitrate, basic(8003-05-2)
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 急性毒性:皮下-大鼠 LD50: 56 毫克/公斤; 静脉-小鼠 LD50: 27 毫克/公斤
  • 毒性分级:高毒
  • 上游原料:苯基醋酸汞
  • 用途一:在医药工业用作防腐剂和避孕药的原料。 #EndEditable "Content"
  • MOL 文件:8003-05-2.mol
  • Sigma Aldrich:8003-05-2(sigmaaldrich)
  • 用途二:用作医药工业，如作防腐剂和避孕剂的原料之一，也可以用作除草剂、杀菌剂、熏剂等。
  • 硝酸苯汞价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80101226 碱性硝酸苯汞 100g 220元
  • 微溶于醇，极微溶于水，几乎不溶于醚，可缓慢溶于甘油。
  • Acros Organics:Phenylmercuric nitrate(8003-05-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organomercury - Organometallic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organomercury - Organometallic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. N-P - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PER - POLA - P
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PER - POLA - P
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Titrimetry - Analytical Standards
  4. Karl Fischer Titration (Hydranal®)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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