Diphenyliodonium trifluoromethanesulfonate 二苯基碘三氟甲烷磺酸盐

CAS 66003-76-7 MFCD00191356

化学结构图

66003-76-7
SMILES: O=S(=O)([O-])C(F)(F)F.c1ccc([I+]c2ccccc2)cc1

化学属性

Mol. FormulaC13H10F3IO3S
Mol. Weight430
Melting Point177-183
TSCANo

别名和识别编码

Chemical NameDiphenyliodonium trifluoromethanesulfonate
Synonym DPIT DPIT 二苯基碘三氟甲烷磺酸盐 Diphenyliodonium trifluoromethanesulfonate 二苯基碘三氟甲烷磺酸盐
CAS Number66003-76-7
PubChem Substance ID87568690
Beilstein Registry Number3582403
MDL NumberMFCD00191356
Reaxys-RN3582403
Chemical Name Translation二苯基碘三氟甲烷磺酸盐
LabNetwork Molecule IDLN03264552
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分类

  • {SNA} Cationic Photoinitiators, Materials Science, Micro/NanoElectronics, Organic Photoinitiators, Photoacid Generators (PAGs),
  • {SNA} Cationic Photoinitiators, Micro/NanoElectronics, Organic Photoinitiators, Photoacid Generators (PAGs), Photoresists, Polymer Science, Polymerization Initiators, Reagents fo

相关文献及参考

  • In the presence of CuCN, Li enolates of cyclic ketones undergo ɑ-phenylation at low temperatures to give the ɑ-phenyl or ɑɑ-diphenyl derivatives: Tetrahedron Lett., 38, 5061 (1997).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
UN Number UN2811
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Light Sensitive
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Hypervalent Iodine - Oxidation
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Organic Photoinitiators - Polymerization Initiators
  5. Cationic Photoinitiators - Organic Photoinitiators
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Hypervalent Iodine Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Iodonium, Sulfonium & Oxonium Compounds
  1. Materials Science 材料科学
  2. Photopolymerization Initiators

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