2-[N,N-BIS(TRIFLUOROMETHYLSULFONYL)AMINO]PYRIDINE 2-[N,正双(三氟甲烷磺酰)氨基]吡啶

CAS 145100-50-1 MFCD00191834

化学结构图

145100-50-1
SMILES: O=S(=O)(N(C1=CC=CC=N1)S(=O)(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC7H4F6N2O4S2
Mol. Weight358
Boiling Point97°/2mm
Melting Point38.0 to 42.0 deg-C
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical Name2-[N,N-BIS(TRIFLUOROMETHYLSULFONYL)AMINO]PYRIDINE
Synonym 2-[N,N-双(三氟甲基磺酰)氨基]吡啶 N,N-双(三氟甲基磺酰基)-2-吡啶胺 2-[N,N-Bis(trifluoromethanesulfonyl)amino]pyridine 2-[N,正双(三氟甲烷磺酰)氨基]吡啶 2-[N,N-Bis(trifluoromethanesulfonyl)amino]pyridineN-(2-Pyridyl)triflimide
MDL NumberMFCD00191834
PubChem Substance ID87564759
Beilstein Registry Number5832565
CAS Number145100-50-1
Reaxys-RN5832565
Chemical Name Translation2-[N,正双(三氟甲烷磺酰)氨基]吡啶
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分类

  • {SNA} Building Blocks, C7, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Reactive triflating agent for conversion of lithium enolates of ketones to vinyl triflates: Tetrahedron Lett., 33, 6299 (1992). Compare 2-[N,N-Bis(trifluoromethyl­sulfonyl)­amino]-5-chloropyridine, L16929.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. C7 to C8 - Pyridines
  1. C6
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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