2-[N,N-BIS(TRIFLUOROMETHYLSULFONYL)AMINO]PYRIDINE 2-[N,正双(三氟甲烷磺酰)氨基]吡啶

CAS 145100-50-1 MFCD00191834

化学结构图

145100-50-1
SMILES: O=S(=O)(N(C1=CC=CC=N1)S(=O)(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC7H4F6N2O4S2
Mol. Weight358
Boiling Point97°/2mm
Melting Point38.0 to 42.0 deg-C
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical Name2-[N,N-BIS(TRIFLUOROMETHYLSULFONYL)AMINO]PYRIDINE
Synonym 2-[N,N-双(三氟甲基磺酰)氨基]吡啶 N,N-双(三氟甲基磺酰基)-2-吡啶胺 2-[N,N-Bis(trifluoromethanesulfonyl)amino]pyridine 2-[N,正双(三氟甲烷磺酰)氨基]吡啶 2-[N,N-Bis(trifluoromethanesulfonyl)amino]pyridineN-(2-Pyridyl)triflimide
MDL NumberMFCD00191834
PubChem Substance ID87564759
Beilstein Registry Number5832565
CAS Number145100-50-1
Reaxys-RN5832565
Chemical Name Translation2-[N,正双(三氟甲烷磺酰)氨基]吡啶
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分类

  • {SNA} Building Blocks, C7, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Reactive triflating agent for conversion of lithium enolates of ketones to vinyl triflates: Tetrahedron Lett., 33, 6299 (1992). Compare 2-[N,N-Bis(trifluoromethyl­sulfonyl)­amino]-5-chloropyridine, L16929.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive
Hazard Codes Xi

系列性分类


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