Dilithium tetrabromonickelate(II) 四溴镍酸二锂(II)

CAS 13826-95-4 MFCD00192058

化学结构图

13826-95-4
SMILES: [Li+].[Li+].Br[Ni-2](Br)(Br)Br

化学属性

Mol. FormulaLi2NiBr4
Mol. Weight392.19
Boiling Point67 °C
Density1.065 g/mL at 25 °C

别名和识别编码

Chemical NameDilithium tetrabromonickelate(II)
Synonym 四溴镍酸二锂(II) 溶液 二锂四溴镍酸盐(II) 锂四溴镍酸盐(II) 溶液 二锂四溴镍酸盐(II) 锂四溴镍酸盐(II) 溶液
CAS Number13826-95-4
PubChem Substance ID24866440
MDL NumberMFCD00192058
Chemical Name Translation四溴镍酸二锂(II)
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分类

  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Lithium Salts, Materials Science, Metal and Ceramic Science, Nickel, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Lithium Salts, Metal and Ceramic Science, Nickel Catalysts, Research Essentials, Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Lithium Salts, Materials Science, Metal and Ceramic Science, Nickel,
  • {SNA} Catalysis and Inorganic

相关文献及参考

  • 1. L. M. Urbanczyk-Pearson and T. J. Meade, Nat. Protoc. 3 , 341-350, (2008)
  • 2. T. Higuchi, et al., Chem. Lett. 35 , 1006-1007, (2006)
  • 3. S. Rigolet, et al., Tetrahedron Lett. 43 , 8129-8132, (2002)
  • 4. Z. X. Guo, et al., Synlett 8 , 607-608, (1993)

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,T
Hazard statements
  • H350 May cause cancer 可能致癌
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P235
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R45 May cause cancer 可能致癌
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Lithium Salts 锂盐

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