(S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde (S)-(-)-3-(叔丁氧羰基)-4-甲酰-2,2-二甲基-1,3-噁唑烷

CAS 102308-32-7 MFCD00209557

化学结构图

102308-32-7
SMILES: CC(C)(C)OC(=O)N1[C@@H](COC1(C)C)C=O

化学属性

Mol. FormulaC11
Mol. Weight229
Refractive index1.4450 to 1.4470
Boiling Point97°C/1.5mmHg(lit.)
Density1.06
TSCANo
Flash Point107°C(lit.)

别名和识别编码

Chemical Name(S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde
Synonym (S)-(-)-3-Boc-2,2-二甲基噁唑烷-4-甲醛 (-)-N-Boc-N,O-异亚丙基-L-丝氨醛 (-)-N-Boc-N,O-异亚丙基-L-丝氨醛 (S)-(-)-4-甲酰基-2,2-二甲基-3-噁唑啉羧酸叔丁酯 Garner 醛 (S)-(-)-3-tert-Butoxycarbonyl-2,2-dimethyloxazolidine-4-carboxaldehyde (S)-(-)-4-甲酰基-2,2-二甲基-3-噁唑啉羧酸叔丁酯
CAS Number102308-32-7
PubChem Substance ID87564654
Beilstein Registry Number3591324
MDL NumberMFCD00209557
Reaxys-RN3591324
Merck Number14,4371
Chemical Name Translation(S)-(-)-3-(叔丁氧羰基)-4-甲酰-2,2-二甲基-1,3-噁唑烷
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分类

  • {SNA} Aldehydes, Asymmetric Synthesis, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Chiral Auxiliaries, Organic Building Blocks, Oxazolidinone Derivatives
  • Aldehydes, Asymmetric Synthesis, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Chiral Auxiliaries, Organic Building Blocks, Oxazolidinone Derivatives

相关文献及参考

  • 1. Hoemann, M.Z. et al. Tetrahedron Lett. 37 , 953, (1996)
  • 2. Roush, W.R. Hunt, J.A. J. Org. Chem. 60 , 798, (1995)
  • 3. Guibourdenche, C. et al. Tetrahedron Asymmetry 4 , 2041, (1993)
  • Merck 14 ,4371
  • FT-IR 2 (1), 1307:A / Structure Index 1 , 140:C:3

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P352+P332+P313+P362+P364
Signal word
Storage condition 0-10 0-10°C Air Sensitive
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Auxiliaries - Asymmetric Synthesis
  4. Oxazolidinone Derivatives - Chiral Auxiliaries
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  6. C10-C12 - Aldehydes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chiral Auxiliaries
  4. Ephedrine Derivatives
  1. Functional Group 官能团索引
  2. hemiaminal

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