Bis(trifluoromethanesulfonyl)imide 双三氟甲烷磺酰亚胺

CAS 82113-65-3 MFCD00214154

化学结构图

82113-65-3
SMILES: O=S(=O)(NS(=O)(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC2HF6NO4S2
Mol. Weight281
Boiling Point90-91
Melting Point52-56
Density1.936

别名和识别编码

Chemical NameBis(trifluoromethanesulfonyl)imide
Synonym 双三氟甲基磺酰亚胺 双(三氟甲烷)磺酰亚胺 双(三氟甲基)硫酰亚胺,N-[(三氟代甲基)磺酰基]-1,1,1-三氟代-甲烷磺酰胺 双(三氟甲基磺酰)胺 双(三氟甲烷磺酰)胺 双三氟甲烷磺酰亚胺 三氟甲烷磺酰亚胺
CAS Number82113-65-3
PubChem Substance ID354334160
Beilstein Registry Number4754101
MDL NumberMFCD00214154
Chemical Name Translation双三氟甲烷磺酰亚胺
LabNetwork Molecule IDLN00200050
Reaxys-RN4754101
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonimides/Sulfinimides, Sulfur Compounds
  • {SA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
  • {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents, Trifluoromethylation

产品应用

  • 强酸,用于制备高效率的路易斯酸催化剂。

相关文献及参考

  • 1. Synlett , 171, (1996)

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P402+P404
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Storage condition 0-10°C 储存温度2-8°C
UN Number 3261
Packing GroupI
Hazard Class8

系列性分类


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