Methyl 4-Chlorobenzoylacetate 4-氯苯甲酰乙酸甲酯

CAS 53101-00-1 MFCD00216520

化学结构图

53101-00-1
SMILES: COC(=O)CC(=O)C1C=CC(Cl)=CC=1

化学属性

Mol. FormulaC10H9ClO3
Mol. Weight212.63
Boiling Point100-106
Melting Point42-46 °C(lit.)

别名和识别编码

Chemical NameMethyl 4-Chlorobenzoylacetate
CAS Number53101-00-1
Alfabeta NameMETHYLCHLOROBENZOYLACETATE 4-
MDL NumberMFCD00216520
Synonym (p-Chlorobenzoyl)acetic acid methyl ester Methyl 3-(4-chlorophenyl)-3-oxopropionate 4-氯苯甲酰乙酸甲酯 Methyl 3-(4-chlorophenyl)-3-oxopropanoate
PubChem Substance ID24881280
Chemical Name Translation4-氯苯甲酰乙酸甲酯
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分类

  • Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SNA} Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • 1. L. Ma, et al., TBAI-catalyzed oxidative coupling of aminopyridines with ß-keto esters and 1,3-diones - synthesis of imidazo[1,2-a]pyridines Chem. Commun. 47 , 11333-11335, (2011)
  • 2. X. Wang, et al., Synthesis of imidazo[1,2-a]pyridines by the bis(acetyloxy)(phenyl)-?3-iodane-mediated oxidative coupling of 2-aminopyridines with ß-keto esters and 1,3-diones Synthesis 15 , 2445-2453, (2011)
  • 3. G. Hou, et al., Highly Efficient Iridium-Catalyzed Asymmetric Hydrogenation of Unprotected ß-Enamine Esters J. Am. Chem. Soc. 132 , 12844-12846, (2010)
  • 4. Y. Chen, et al., Base- and Copper-Catalyzed Intramolecular Cyclization for the Direct Synthesis of Dihydrofurans Adv. Synth. Catal. 352 , 1163-1168, (2010)
  • 5. C. A. Correia and C. Li, Catalytic alkylation of benzylic C-H bonds with 1,3-dicarbonyl compounds utilizing oxygen as terminal oxidant Tetrahedron Lett. 51 , 1172-1175, (2010)
  • 6. X. Guo, et al., Iron-Catalyzed Tandem Oxidative Coupling and Annulation: An Efficient Approach to Construct Polysubstituted Benzofurans J. Am. Chem. Soc. 131 , 17387-17393, (2009)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
Signal word Warning
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
Risk Statements
  • R36 Irritating to eyes 刺激眼睛

系列性分类


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