(S,S)-(-)-Bis(α-methylbenzyl)amine Hydrochloride (S,S)-(-)-双(α-甲苄基)胺盐酸盐

CAS 40648-92-8 MFCD00216671

化学结构图

40648-92-8
SMILES: C[C@H](N[C@@H](C)c1ccccc1)c1ccccc1.Cl

化学属性

Mol. FormulaC16H19N·HCl
Mol. Weight261.79
Melting Point~260 °C

别名和识别编码

Chemical Name(S,S)-(-)-Bis(α-methylbenzyl)amine Hydrochloride
Synonym (-)-双[(S)-α-甲苄基]胺 盐酸盐 (-)-双[(S)-1-苯基乙基]胺 盐酸盐 [S-(R*,R*)]-(-)-双(-α-甲苄基)胺 盐酸盐 [S-(R*,R*)]-(-)-双(-α-甲苄基)胺 盐酸盐
MDL NumberMFCD00216671
PubChem Substance ID87564914
Beilstein Registry Number4723969
CAS Number40648-92-8
Reaxys-RN5857760
Chemical Name Translation(S,S)-(-)-双(α-甲苄基)胺盐酸盐
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分类

  • {SNA} Amine Salts, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • Amine Salts, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

相关文献及参考

  • 1. N.S. Simpkins Chem. Soc. Rev. 19 , 335, (1990)
  • 2. P.J. Cox, N.S. Simpkins Tetrahedron Asymmetry 2 , 1, (1991)
  • 3. M. Majewski, D.M. Gleave J. Org. Chem. 57 , 3599, (1992)
  • 4. T. Honda et al. Tetrahedron Asymmetry 4 , 1475, (1993)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning {} {} {} {} {} {} {} {} {} {TCI}
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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