2-(Diphenylphosphino)ethylamine 2-(二苯基膦基)乙胺

CAS 4848-43-5 MFCD00233831

化学结构图

4848-43-5
SMILES: NCCP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H16NP
Mol. Weight229.26
TSCANo
Density1.422
Appearance 无色或淡黄液体
Stability对湿度敏感
Boiling Point341.1°C at 760 mmHg

别名和识别编码

Chemical Name2-(Diphenylphosphino)ethylamine
Synonym 2-(Diphenylphosphino)ethylamine {LY} 2-(Diphenylphosphino)ethylamine {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Diphenylphosphino)ethy
MDL NumberMFCD00233831
PubChem Substance ID273264
Beilstein Registry Number644931
CAS Number4848-43-5
EC Number250-023-7
Chemical Name Translation2-(二苯基膦基)乙胺
LabNetwork Molecule IDLN00189923
InChIInChI=1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2
Canonical SMILESNCCP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {SNA} Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Phosphine Compounds, Phosphine Ligands, Privileged Ligands and Complexes
  • Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Phosphine Compounds, Phosphine Ligands, Privileged Ligands and Complexes

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes C
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
UN Number 2735 UN2735 UN 2735 8/PG 3
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Packing GroupIII
Hazard Class8

其他信息

  • 存储注意事项:氮气保护;湿度敏感;空气敏感
  • 上游原料:乙醇 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 氧氯化硫 --> 三苯基膦 --> 乙醇胺 --> 锂
  • F:1-10-13
  • 2-(二苯基膦基)乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 H27070 2-(二苯基膦基)乙胺,95% 2-(Diphenylphosphino)ethylamine, 95% 1g 1680元 2010/05/25 H27070 2-(二苯基膦基)乙胺,95% 2-(Diphenylphosphino)ethylamine, 95% 10g 10080元
  • Alfa Aesar:2-(二苯基膦基)乙胺,95% 2-(Diphenylphosphino)ethylamine, 95%(4848-43-5)
  • MOL 文件:4848-43-5.mol
  • 用途一:作为配体,用于制备钌催化剂或其它配合物
  • 敏感性:Moisture Sensitive

系列性分类


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