(R)-4-(chloromethyl)-2,2-dimethyl-1,3-dioxolane (R)-(+)-2,2-二甲基-4-(氯甲基)-1,3-二氧戊环

CAS 57044-24-3 MFCD00273371

化学结构图

57044-24-3
SMILES: CC1(C)OC[C@H](CCl)O1

化学属性

Mol. FormulaC6
Mol. Weight151
Refractive index1.4330 to 1.4370
Boiling Point63
Density1.103
Flash Point51°C(lit.)
TSCANo

别名和识别编码

Chemical Name(R)-4-(chloromethyl)-2,2-dimethyl-1,3-dioxolane
CAS Number57044-24-3
PubChem Substance ID87560775
MDL NumberMFCD00273371
Reaxys-RN4654188
Beilstein Registry Number4654188
Synonym (R)-(+)-3-Chloro-1,2-propanediol acetonide (R)-(+)-4-(氯甲基)-2,2-二甲基-1,3-二氧戊环
Chemical Name Translation(R)-(+)-2,2-二甲基-4-(氯甲基)-1,3-二氧戊环
LabNetwork Molecule IDLN00236784
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols

相关文献及参考

  • 1. Camps, P. et al. Tetrahedron Asymmetry 6 , 1283, (1995)
  • Beil. 19 ,IV,70

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1992 1993
Risk Statements
  • R10 Flammable 易燃
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Packing GroupIII
Hazard Class3/6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks

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