2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane 95% 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
CAS 14812-59-0 MFCD00274239
化学结构图
SMILES: CC1(C)OP(Cl)OC1(C)C
化学属性
| Mol. Formula | C6H12ClO2P |
|---|---|
| Mol. Weight | 182.59 |
| Refractive index | n20/D 1.471(lit.) |
| Boiling Point | 81.5-82 °C/13 mmHg(lit.) |
| Density | 1.149 g/mL at 25 °C(lit.) |
别名和识别编码
| Chemical Name | 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane 95% |
|---|---|
| Synonym | 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane {uni_hamburg} chlorophosphoric acid-(tetramethyl-ethanediyl ester) 4,4,5,5-Tetramethyl-2-chloro-1,3,2-dioxaphospholane 1,3,2-Dioxaphospholane, 2-chloro-4,4,5,5-tetramethyl- 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷 |
| PubChem Substance ID | 24868346 |
| MDL Number | MFCD00274239 |
| Chemical Name Translation | 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷 |
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分类
- {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 5ring; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S22 Do not breathe dust 不要吸入粉尘；
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