Bis(norbornadiene)rhodium(I) tetrafluoroborate 双(降冰片二烯)四氟硼酸铑(I)

CAS 36620-11-8 MFCD00671775

化学结构图

36620-11-8
SMILES: [Rh+].F[B-](F)(F)F.C1[C@@H]2C=C[C@H]1C=C2.C1[C@@H]2C=C[C@H]1C=C2 |&1:7,10,14,17|

化学属性

Mol. FormulaRh(C7H8)2+BF4ae
Mol. Weight374
Melting Point137-139
TSCANo
Density1.422

别名和识别编码

Chemical NameBis(norbornadiene)rhodium(I) tetrafluoroborate
Synonym Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate Bis(norbornadiene)(tetrafluoroborato)rhodium Rh(nbd)2BF4 Rh(nbd)2BF4 Rh(nbd)2BF4 Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate, Bis(norbornadiene)(tetrafluoroborato)rhodium 双(降冰片二烯)四氟硼酸铑(I) Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate
MDL NumberMFCD00671775
PubChem Substance ID87564962
CAS Number36620-11-8
EC Number250-023-7
Beilstein Registry Number14305268
Reaxys-RN14305268
Chemical Name Translation双(降冰片二烯)四氟硼酸铑(I)
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
Storage condition 0-10 Air & Moisture Sensitive 0-10°C
Hazard Codes C
UN Number 1759
Packing GroupIII
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Volumetric Concentrates (e.g. FIXANAL®) - Titration
  5. Salt Concentrates - Volumetric Concentrates (e.g. FIXANAL®)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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