Bis(dichlorophosphino)methane 双(二氯膦基)甲烷
CAS 28240-68-8 MFCD01073767
化学结构图
SMILES: ClP(Cl)CP(Cl)Cl
化学属性
| Refractive index | n20/D 1.5940(lit.) |
|---|---|
| Mol. Formula | CH2Cl4P2 |
| Mol. Weight | 217.78 |
| Density | 1.601 |
| Appearance | colorless liq. |
| Stability | air sensitive, moisture sensitive |
| Boiling Point | 101-105°C/22mm |
别名和识别编码
| Chemical Name | Bis(dichlorophosphino)methane |
|---|---|
| Synonym | {uni_hamburg} methylenebis(dichlorophophine) methylenebis(dichlorophosphane) Methylenebisphosphonous dichloride Bis(dichlorophosphino)methane Methylenebis(phosphonous dichloride) Methylenebis(dichlorophosphine) Methylenebis(phosphonous dichloride) Tetrachlormethylenbisphosphan 双(二氯磷氢基)甲烷 |
| PubChem Substance ID | 24868600 |
| Chemical Name Translation | 双(二氯膦基)甲烷 |
| MDL Number | MFCD01073767 |
| CAS Number | 28240-68-8 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
安全信息
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
GHS Symbol
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
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