(R)-2,2’-Bis(Di-P-Tolylphosphino)-1,1‘-Binaphthalene (R)-2,2’-双(二对甲苯基膦基)-1,1‘-联萘

CAS 99646-28-3 MFCD01311709

化学结构图

99646-28-3
SMILES: Cc1ccc(P(c2ccc(C)cc2)c2ccc3ccccc3c2-c2c(P(c3ccc(C)cc3)c3ccc(C)cc3)ccc3ccccc23)cc1

化学属性

Mol. FormulaC48H40P2
Mol. Weight678.78
Melting Point254-258 °C
TSCANo
Stability对湿度和空气敏感
Appearance white pwdr.

别名和识别编码

Chemical Name(R)-2,2’-Bis(Di-P-Tolylphosphino)-1,1‘-Binaphthalene
Synonym (S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘 (R)-Tol-BINAP (R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘 (S)-(-)-2, 2-双（二对甲苯基膦）-1,1-二联萘 (S)-T-BINAP (R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘 (R)-T-BINAP (S)-(-)-2,2'-双(二对甲苯基膦)-1,1'-联萘;(S)-Tol-BINAP (R)-Tol-BINAP (S)-Tol-BINAP rac-p-Tol-BINAP (S)-Tol-BINAP (S)-(-)-2,2′-双(二对甲苯基膦)-1,1'-二联萘
MDL NumberMFCD01311709
CAS Number99646-28-3
PubChem Substance ID4189906
Chemical Name Translation(R)-2,2’-双(二对甲苯基膦基)-1,1‘-联萘
Reaxys-RN5786040
InChIInChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Related Palladacycles, Asymmetric Synthesis, BINAPs, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cross-Coupling, Privileged Ligands and Complexes

安全信息

WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 储存温度2-8℃,充氩保存

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. BINAP
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. BINAP
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Ligands
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Phosphine
  2. 96-6950 Takasago BINAP Ligand Kit

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