(S)-2,2’-Bis(bis(3,5-Dimethylphenyl)Phosphino)-1,1’-Binaphthalene (S)-2,2’-双[二(3,5-二甲基苯基膦)]-1,1’-联萘

CAS 135139-00-3 MFCD01630821

化学结构图

135139-00-3
SMILES:

化学属性

Mol. FormulaC52H48P2
Mol. Weight734.89
Melting Point189-193 °C
TSCANo
Appearance white to pale yellow xtl.

别名和识别编码

Chemical Name(S)-2,2’-Bis(bis(3,5-Dimethylphenyl)Phosphino)-1,1’-Binaphthalene
Synonym (R)-(+)-1,1′-联萘-2,2′-二基)二[双(3,5-二甲基苯基)膦] (R)-(+)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘 (R)-Xylyl-BINAP (S)-(-)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘 (S)-DM-BINAP (S)-联萘(3,5-二甲苯基)膦 (S)-联萘(3,5-二甲苯基)膦 (S)-(-)-2,2′-双[二(3,5-二甲苯基)膦]-1,1′-联萘
MDL NumberMFCD01630821
CAS Number135139-00-3
Chemical Name Translation(S)-2,2’-双[二(3,5-二甲基苯基膦)]-1,1’-联萘
Reaxys-RN4344206
PubChem Substance ID329761554
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • Evans, P. A.; et al., Regiodivergent Ligand-Controlled Rhodium-Catalyzed [(2+2)+2] Carbocyclization Reactions with Alkyl Substituted Methyl Propiolates Angew. Chem. Int. Ed. Engl. 49 , 5746-5749, (2010)
  • Goto, M.; et al., Process Research on the Asymmetric Hydrogenation of a Benzophenone for Developing the Manufacturing Process of the Squalene Synthase Inhibitor TAK-475 Org. Process Res. Dev. 15 , 1178-1184, (2011)
  • Kiyooka, S.; et al., Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature Tetrahedron 66 , 1806-1816, (2010)
  • Menard, F.; et al., Ligand-Controlled Selectivity in the Desymmetrization of meso Cyclopenten-1,4-diols via Rhodium(I)-Catalyzed Addition of Arylboronic Acids J. Org. Chem. 75 , 4056-4068, (2010)
  • Ogaki, S.; et al., Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition J. Org. Chem. 76 , 1926-1929, (2011)
  • Oppenheimer, J.; et al., A rhodium(I)-xylyl-BINAP catalyzed asymmetric ynamide-[2+2+2] cycloaddition in the synthesis of optically enriched N,O-biaryls Tetrahedron 65 , 5001-5012, (2009)

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. BINAP
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. BINAP
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Ligands
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Phosphine
  2. 96-6950 Takasago BINAP Ligand Kit

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